"000308513000064" . . "Asymmetric Transfer Hydrogenation of Acetophenone N-Benzylimine Using [(RuCl)-Cl-II((S,S)-TsDPEN)(eta(6)-p-cymene)]: A DFT Study" . "4"^^ . . . "10.1021/om300413n" . "\u0160ot, P." . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . "7"^^ . "V\u00E1clav\u00EDk, J." . "Pech\u00E1\u010Dek, J." . "Asymmetric Transfer Hydrogenation of Acetophenone N-Benzylimine Using [(RuCl)-Cl-II((S,S)-TsDPEN)(eta(6)-p-cymene)]: A DFT Study"@en . "Asymmetric transfer hydrogenation of the acyclic imine acetophenone N-benzylimine was studied by means of computational chemistry. Calculated transition states offer an explanation of why this prochiral imine leads to the delivery of (S)-amine (when using (S,S)-TsDPEN ligand) rather than (R)-amine, which is common for endocyclic imines (e.g., substituted 3,4-dihydroisoquinolines or 3,4-dihydro-beta-carbolines). This study extends our previous investigation of the so-called ionic mechanism" . "RIV/61388971:_____/12:00390161" . . . . "I, P(GA104/09/1497), P(GAP106/12/1276)" . "P\u0159ech, J." . . "Asymmetric transfer hydrogenation of the acyclic imine acetophenone N-benzylimine was studied by means of computational chemistry. Calculated transition states offer an explanation of why this prochiral imine leads to the delivery of (S)-amine (when using (S,S)-TsDPEN ligand) rather than (R)-amine, which is common for endocyclic imines (e.g., substituted 3,4-dihydroisoquinolines or 3,4-dihydro-beta-carbolines). This study extends our previous investigation of the so-called ionic mechanism"@en . "0276-7333" . "123956" . "17" . "1"^^ . "Asymmetric Transfer Hydrogenation of Acetophenone N-Benzylimine Using [(RuCl)-Cl-II((S,S)-TsDPEN)(eta(6)-p-cymene)]: A DFT Study" . . "Kuzma, Marek" . . . . . "Asymmetric Transfer Hydrogenation of Acetophenone N-Benzylimine Using [(RuCl)-Cl-II((S,S)-TsDPEN)(eta(6)-p-cymene)]: A DFT Study"@en . . . "Ka\u010Der, P." . "RIV/61388971:_____/12:00390161!RIV13-GA0-61388971" . . "[36F9D4F64C79]" . . "CARBONYL-COMPOUNDS; KETONES; IMINES"@en . "Organometallics" . . . "31" . "Janu\u0161\u010D\u00E1k, J." .