. . "dynamic stereochemistry; kinetic [2+2+2] cycloaddition; DFT and spectroscopy"@en . "RIV/61388963:_____/11:00363302!RIV12-AV0-61388963" . . "Escudero-Ad\u00E1n, E. C." . . . . . . "Novotn\u00E1, P." . "12" . . . "Pohl, Radek" . "RIV/61388963:_____/11:00363302" . . "S\u00E1zelov\u00E1, Petra" . . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . . "[6]Saddlequat: a [6]helquat captured on its racemization pathway" . . "\u0160aman, David" . "Koval, Du\u0161an" . . "Adriaenssens, Louis" . . "9"^^ . "[5F7B733B74E7]" . "14"^^ . "A dicationic [6]helicene congener captured on the racemization pathway in its saddle-shaped geometry is introduced. The dynamic aspects established by experiment and supported by detailed DFT-D calculations are presented visually in the form of a movie (electronic table-of-contents and electronic supplementary information). The title [6]saddlequat was found to be an isolable chiral species on the entirely chiral enantiomerization pathway of a [6]helquat that is discussed as an example of Mislow\u2019s rubber glove\u2019\u2019 molecule." . "Chemical Science" . . . . "Urbanov\u00E1, M." . . . "Severa, Luk\u00E1\u0161" . "2" . "A dicationic [6]helicene congener captured on the racemization pathway in its saddle-shaped geometry is introduced. The dynamic aspects established by experiment and supported by detailed DFT-D calculations are presented visually in the form of a movie (electronic table-of-contents and electronic supplementary information). The title [6]saddlequat was found to be an isolable chiral species on the entirely chiral enantiomerization pathway of a [6]helquat that is discussed as an example of Mislow\u2019s rubber glove\u2019\u2019 molecule."@en . "10.1039/c1sc00468a" . "000296745500005" . . "2041-6520" . . . "[6]Saddlequat: a [6]helquat captured on its racemization pathway" . "8"^^ . . "Tepl\u00FD, Filip" . "V\u00E1vra, Jan" . . "244241" . "C\u00EDsa\u0159ov\u00E1, I." . "Adriaenssens, Louis" . "P(GA203/08/1428), P(GA203/09/1614), P(GAP207/10/2391), P(GP203/09/P485), S, Z(AV0Z40550506), Z(MSM0021620857)" . "[6]Saddlequat: a [6]helquat captured on its racemization pathway"@en . "Ka\u0161i\u010Dka, V\u00E1clav" . "[6]Saddlequat: a [6]helquat captured on its racemization pathway"@en . "Belmonte, M. M." . . . . .