. . . . "391286" . . . "Kvaziplanarita peptidov\u00E9 vazby"@cs . "\u0160pirko, Vladim\u00EDr" . "RIV/61388963:_____/08:00315508!RIV09-AV0-61388963" . "RIV/61388963:_____/08:00315508" . "7"^^ . . . . "Quasiplanarity of the peptide bond" . "4" . . "3"^^ . . "The vibrational motions of the model peptide unit represented by the main-chain carbonyl carbon, oxygen, nitrogen, and amide hydrogen are analyzed quantum-mechanically using formamide, cis-N-methylformamide, trans-N-methylformamide, NN-dimethylformamide, L-alanyl-L-alanine, and N-benzoylphenylalanine as dynamical models. Importantly, the simplest dynamical (one-dimensional) problem based on the separation of the amide out-of-plane motion from the rest of the peptide unit motions allows for a physically correct description of the effective %22ground state%22 molecular geometry of all studied systems." . . . . "Chalupsk\u00FD, Jakub" . "Quasiplanarity of the peptide bond" . . "The vibrational motions of the model peptide unit represented by the main-chain carbonyl carbon, oxygen, nitrogen, and amide hydrogen are analyzed quantum-mechanically using formamide, cis-N-methylformamide, trans-N-methylformamide, NN-dimethylformamide, L-alanyl-L-alanine, and N-benzoylphenylalanine as dynamical models. Importantly, the simplest dynamical (one-dimensional) problem based on the separation of the amide out-of-plane motion from the rest of the peptide unit motions allows for a physically correct description of the effective %22ground state%22 molecular geometry of all studied systems."@en . "3"^^ . . "Journal of Physical Chemistry A" . "000252618700015" . "Quasiplanarity of the peptide bond"@en . "112" . "coupled-cluster singles; gas electron-diffraction; alanyl-L-alanine; molecular structure; microwawe spectrum"@en . . "Quasiplanarity of the peptide bond"@en . . "P(GA203/06/0420), P(GA203/06/1727), P(IAA400550702), P(LC512), Z(AV0Z40550506)" . . "[AA6C88A9AF92]" . . . "Kvaziplanarita peptidov\u00E9 vazby"@cs . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . . "Vondr\u00E1\u0161ek, Ji\u0159\u00ED" . . . "1089-5639" . "Vibra\u010Dn\u00ED pohyby modelu peptidov\u00E9 vazby reprezentovan\u00E9 atomy hlavn\u00EDho \u0159et\u011Bzce C,N,O a H byly analyzov\u00E1ny metodami kvantov\u00E9 v\u00FDpo\u010Detn\u00ED chemie na dynamick\u00FDch modelov\u00FDch syst\u00E9mech jako je formamid, cis-N-methylformamid, trans-N-methylformamid, NN-dimethylformamid, L-alanyl-L-alanine a N-benzoylphenylalanin . Nejjednodu\u0161\u00ED dynamick\u00FD (jednodimension\u00E1ln\u00ED) problem zalo\u017Een\u00FD na separatovatelnosti amidov\u00E9 out-of-plane vibrace od zbytku peptide dovoluje fyzik\u00E1ln\u011B koretn\u00ED popis efektivn\u00EDho z\u00E1kladn\u00EDho stavu molekul\u00E1rn\u00ED geometrie studovan\u00E9ho system."@cs .