"0010-0765" . "Revision of the dual-substituent-parameter treatment ; reaction series with a donor reaction centre" . "Z(AV0Z40550506), Z(MSM6046137301)" . . "Revision of the dual-substituent-parameter treatment ; reaction series with a donor reaction centre"@en . . "447714" . "1158;1176" . "Revize metody du\u00E1ln\u00EDch substitu\u010Dn\u00EDch parametr\u016F: reak\u010Dn\u00ED serie s reak\u010Dn\u00EDm centrem charakteru donoru"@cs . . . "1"^^ . "Collection of Czechoslovak Chemical Communications" . "Revision of the dual-substituent-parameter treatment ; reaction series with a donor reaction centre"@en . "CZ - \u010Cesk\u00E1 republika" . . . "Metoda du\u00E1ln\u00EDch substitu\u010Dn\u00EDch parametr\u016F (DSP) byla revidov\u00E1na na reakc\u00EDch s reak\u010Dn\u00EDm centrem charakteru donoru, jako je bazicita a acidita substituovan\u00FDch anilin\u016F a acidita substituovan\u00FDch fenol\u016F. Substitu\u010Dn\u00ED efekty byly vypo\u010Dteny metodou DFT separ\u00E1tn\u011B v nenabit\u00FDch molekul\u00E1ch a v iontech. DSP plat\u00ED pro acidity a pro neutr\u00E1ln\u00ED molekuly jen s akceptorov\u00FDmi substituenty; donorov\u00E9 substituenty nemohou b\u00FDt charakterizov\u00E1ny pomoc\u00ED rezonan\u010Dn\u00EDch konstant. Doporu\u010Duje se u\u017E\u00EDval DSP jen pro akcetporov\u00E9 substituenty p\u0159i donorov\u00E9m reak\u010Dn\u00EDm centru a naopak, jinak se p\u0159esnost pov\u00E1\u017Eliv\u011B sni\u017Euje."@cs . "Exner, Otto" . "2"^^ . "Revize metody du\u00E1ln\u00EDch substitu\u010Dn\u00EDch parametr\u016F: reak\u010Dn\u00ED serie s reak\u010Dn\u00EDm centrem charakteru donoru"@cs . . . "9"^^ . . . . . "Revision of the dual-substituent-parameter treatment ; reaction series with a donor reaction centre" . "[CFD3A0294E4E]" . . "The Dual-Substituent-Parameter (DSP) treatment was reexamined on reactions with a donor reaction centre: basicity and acidity of 4-substituted anilines and acidity of 4-substituted phenols. The substituent effects were calculated by the DFT method separately in uncharged molecules and in the ions. DSP is valid for the acidities and for neutral molecules only with acceptor substituents; donor substituents cannot be characterized by resonance constants. It is recommended to use DSP only to acceptor substituents with a donor reaction centre or vice versa; otherwise the accuracy is much lowered." . . "B\u00F6hm, S." . . "8" . . "aniline derivatives; isodesmic reactions; phenol derivatives; basicity; acidity"@en . "72" . "RIV/61388963:_____/07:00087621" . "RIV/61388963:_____/07:00087621!RIV08-AV0-61388963" . "The Dual-Substituent-Parameter (DSP) treatment was reexamined on reactions with a donor reaction centre: basicity and acidity of 4-substituted anilines and acidity of 4-substituted phenols. The substituent effects were calculated by the DFT method separately in uncharged molecules and in the ions. DSP is valid for the acidities and for neutral molecules only with acceptor substituents; donor substituents cannot be characterized by resonance constants. It is recommended to use DSP only to acceptor substituents with a donor reaction centre or vice versa; otherwise the accuracy is much lowered."@en . . .