"6" . . "The [2+2+2] cyclotrimerization of 1-isoquinolinyl-1,7-octadiyne with benzonitrile catalyzed by CpCo(CO)2 opened a new pathway for a synthesis of unsymmetrical axially chiral bipyridine N,N\u2019-dioxides. The N,N\u2019-dioxide 3a was found to be highly catalytically active and enantioselective for the asymmetric allylation of aldehydes with allyltrichlorosilane. The allylation took place with even 1% of the catalyst with an enantioselectivity up to 87% ee." . . . . "allylation; asymmetric catalysis; Lewis bases"@en . "Kotora, Martin" . "RIV/61388963:_____/07:00081291!RIV07-AV0-61388963" . . "A simple approach to unsymmetric atropoisomeric bipyridine N,N'-dioxides and their application in enantioselective allylation of aldehydes" . "The [2+2+2] cyclotrimerization of 1-isoquinolinyl-1,7-octadiyne with benzonitrile catalyzed by CpCo(CO)2 opened a new pathway for a synthesis of unsymmetrical axially chiral bipyridine N,N\u2019-dioxides. The N,N\u2019-dioxide 3a was found to be highly catalytically active and enantioselective for the asymmetric allylation of aldehydes with allyltrichlorosilane. The allylation took place with even 1% of the catalyst with an enantioselectivity up to 87% ee."@en . "[C5DF46B97A34]" . . "DE - Spolkov\u00E1 republika N\u011Bmecko" . . "Jednoduch\u00FD p\u0159\u00EDstup k nesymetrick\u00FDm atropoisomern\u00EDm bipyridin N,N\u2019-dioxid\u016Fm a pou\u017Eit\u00ED v enantioselektivn\u00ED allylaci aldehyd\u016F"@cs . "C\u00EDsa\u0159ov\u00E1, I." . "Hrdina, R." . "A simple approach to unsymmetric atropoisomeric bipyridine N,N'-dioxides and their application in enantioselective allylation of aldehydes"@en . "822;826" . . . "A simple approach to unsymmetric atropoisomeric bipyridine N,N'-dioxides and their application in enantioselective allylation of aldehydes" . . . "RIV/61388963:_____/07:00081291" . . . "408180" . "A simple approach to unsymmetric atropoisomeric bipyridine N,N'-dioxides and their application in enantioselective allylation of aldehydes"@en . . . . "5"^^ . "349" . . . "5"^^ . "Advanced Synthesis & Catalysis" . "P(GA203/05/0102), P(LC06070), Z(AV0Z40550506), Z(MSM0021620857)" . "1615-4150" . "2+2+2-Cyklotrimerizace 1-isochinolinyl-1,7-oktadiynu s benzonitrilem katalyzovan\u00E1 CpCo(CO)2 otev\u0159ela novou cestu k synt\u00E9ze nesymetrick\u00FDch axi\u00E1ln\u011B chir\u00E1ln\u00EDch bipyridin N,N\u2019-dioxid\u016F. N,N\u2019-dioxid 3a je vysoce katalyticky aktivn\u00ED a enantioselektivn\u00ED v asymetrick\u00E9 allylaci aldehyd\u016F allyltrichlorosilanem. Allylace prob\u00EDh\u00E1 i s 1% katalyz\u00E1toru s enantioselektivitou a\u017E 87% ee."@cs . "Jednoduch\u00FD p\u0159\u00EDstup k nesymetrick\u00FDm atropoisomern\u00EDm bipyridin N,N\u2019-dioxid\u016Fm a pou\u017Eit\u00ED v enantioselektivn\u00ED allylaci aldehyd\u016F"@cs . . . "3"^^ . "Hoda\u010Dov\u00E1, Jana" . "Valterov\u00E1, Irena" . .