. "Basicita karboxylov\u00FDch kyselin: resonance v kationtu a substitu\u010Dn\u00ED efekty"@cs . "7"^^ . . "Basic properties of acetic, formic and substituted benzoic acids were investigated by DFT calculations. The protonated form prefers unsymmetrical conformation E,Z. Lower basicity of carboxylic acids as compared to ketones is due to the higher energy of the cation while the effect in the uncharged acid molecule is negligible. Contribution of resonance and of the inductive effect was approximately estimated."@en . . "[703D33A051CA]" . . "Basicity of carboxylic acids: resonance in the cation and substituent effects"@en . . . "-" . "Exner, Otto" . "Basicity of carboxylic acids: resonance in the cation and substituent effects" . "513567" . "336;342" . "RIV/61388963:_____/05:00021120!RIV06-MSM-61388963" . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . . "Basicita karboxylov\u00FDch kyselin: resonance v kationtu a substitu\u010Dn\u00ED efekty"@cs . "P(LN00A032), Z(AV0Z4055905), Z(MSM6046137301)" . "Basick\u00E9 vlastnosti kyseliny octov\u00E9, mraven\u010D\u00ED a substituovan\u00FDch kyselin benzoov\u00FDch byly zkoum\u00E1ny DFT v\u00FDpo\u010Dty. Protonovan\u00E9 formy preferuj\u00ED nesymetrickou konformaci E,Z. Ni\u017E\u0161\u00ED basicita karboxylov\u00FDch kyselin ve srovn\u00E1n\u00ED s ketony je zp\u016Fsobena vy\u0161\u0161\u00ED energi\u00ED kationtu, zat\u00EDmco vliv na neutr\u00E1ln\u00ED molekulu je zanedbateln\u00FD. P\u0159ibli\u017En\u011B byl odhadnut pod\u00EDl induktivn\u00EDho efektu a resonance."@cs . "Basicity of carboxylic acids: resonance in the cation and substituent effects" . . "2"^^ . . . . . "1144-0546" . "29" . "basicity; carboxylic acids"@en . "1"^^ . . "RIV/61388963:_____/05:00021120" . "New Journal of Chemistry" . "Basic properties of acetic, formic and substituted benzoic acids were investigated by DFT calculations. The protonated form prefers unsymmetrical conformation E,Z. Lower basicity of carboxylic acids as compared to ketones is due to the higher energy of the cation while the effect in the uncharged acid molecule is negligible. Contribution of resonance and of the inductive effect was approximately estimated." . . "Basicity of carboxylic acids: resonance in the cation and substituent effects"@en . . . "B\u00F6hm, S." . .