. "Kub\u016F, Martin" . "zeolite CIT-5; titanosilicate; epoxidation"@en . . . "RIV/61388955:_____/14:00427877!RIV15-GA0-61388955" . "Titanium containing extra-large pore zeolite CIT-5 (IZA code: CFI) was successfully prepared by direct synthesis using Cab-O-Sil M5 and titanium(IV) butoxide in the presence of LiOH. N-Methylsparteinium hydroxide was used as a structure directing agent. The product crystallized into thin plate crystals with an approximate size of 20 x 5 x 0.2 mu m. The lowest achieved Si/Ti ratio was 23. The necessary duration of hydrothermal synthesis increased with increasing concentration of Ti in the reaction mixture from 11 days (Si/Ti = 63 in product) to 17 days (Si/Ti = 36) at 155 degrees C. Prepared Ti-CFI samples exhibit BET surface areas in the range of 308-346 m(2)/g and micropore volumes of 0.094-0.097 cm(3)/g. CFI possesses extralarge pores (14-ring, 7.2 x 7.5 A) accessible for bulky molecules, therefore, Ti-CFI is a useful catalyst for epoxidation of double bonds in bulky molecules used in perfumery and pharmacy. The Ti-CFI samples proved to be catalytically active in epoxidation of 1-octene, cyclooctene, cv-pinene, and norbornene with hydrogen peroxide as oxidation agent."@en . . "227" . "\u010Cejka, Ji\u0159\u00ED" . "Synthesis and catalytic properties of titanium containing extra-large pore zeolite CIT-5" . "3"^^ . "3"^^ . "Catalysis Today" . "Synthesis and catalytic properties of titanium containing extra-large pore zeolite CIT-5"@en . . . "I, P(GBP106/12/G015)" . . "Synthesis and catalytic properties of titanium containing extra-large pore zeolite CIT-5" . "48964" . . "10.1016/j.cattod.2014.01.003" . "MAY 2014" . "000332412900013" . . . "0920-5861" . "[31D89801729D]" . "Synthesis and catalytic properties of titanium containing extra-large pore zeolite CIT-5"@en . "NL - Nizozemsko" . "P\u0159ech, Jan" . . . . . . "Titanium containing extra-large pore zeolite CIT-5 (IZA code: CFI) was successfully prepared by direct synthesis using Cab-O-Sil M5 and titanium(IV) butoxide in the presence of LiOH. N-Methylsparteinium hydroxide was used as a structure directing agent. The product crystallized into thin plate crystals with an approximate size of 20 x 5 x 0.2 mu m. The lowest achieved Si/Ti ratio was 23. The necessary duration of hydrothermal synthesis increased with increasing concentration of Ti in the reaction mixture from 11 days (Si/Ti = 63 in product) to 17 days (Si/Ti = 36) at 155 degrees C. Prepared Ti-CFI samples exhibit BET surface areas in the range of 308-346 m(2)/g and micropore volumes of 0.094-0.097 cm(3)/g. CFI possesses extralarge pores (14-ring, 7.2 x 7.5 A) accessible for bulky molecules, therefore, Ti-CFI is a useful catalyst for epoxidation of double bonds in bulky molecules used in perfumery and pharmacy. The Ti-CFI samples proved to be catalytically active in epoxidation of 1-octene, cyclooctene, cv-pinene, and norbornene with hydrogen peroxide as oxidation agent." . . . "RIV/61388955:_____/14:00427877" . "7"^^ . .