"6"^^ . "Kubi\u0161ta, Ji\u0159\u00ED" . "Decamethylchromocene [Cr(\u03B75-C5Me5)2] reacted with cyclopentadienyltitaniumtrichlorides [Ti(\u03B75-C5H5-nMen)Cl3] (n=0\u20135) in toluene to precipitate yellow finely crystalline ion pairs [Cr(\u03B75-C5Me5)2]+[Ti(\u03B75-C5H5-nMen)Cl3] (1\u20136). Evidence for the chromocenium cation and titanate anions was obtained by paramagnetic 1H NMR spectra of 1\u20136 in CD2Cl2. The resonance of the cation was invariant at \u03B4 6.9 ppm (\u0394\u03BD1/20.4 kHz) whereas resonances of the titanate anions were shifting in response to the number of methyl groups (\u03B4 10.5\u20138.4 ppm (CpMe) and \u03B4 26.6\u201339.0 ppm (CpH)). The presence of toluene of crystallization in 1\u20136 was observed by 1H NMR spectra, and in the crystal structure of 6. Crystallization of 6 from tetrahydrofuran afforded solvent-free crystals of 6A. In crystal structures of both 6 and 6A the [Ti(\u03B75-C5Me5)Cl3]\u2013 titanate anion possessed shorter Ti\u2013Cg distances and longer Ti\u2013Cl bonds than the neutral species." . . . . "Ion pairs from redox reaction of decamethylchromocene with cyclopentadienyltitanium trichlorides"@en . . "Decamethylchromocene [Cr(\u03B75-C5Me5)2] reacted with cyclopentadienyltitaniumtrichlorides [Ti(\u03B75-C5H5-nMen)Cl3] (n=0\u20135) in toluene to precipitate yellow finely crystalline ion pairs [Cr(\u03B75-C5Me5)2]+[Ti(\u03B75-C5H5-nMen)Cl3] (1\u20136). Evidence for the chromocenium cation and titanate anions was obtained by paramagnetic 1H NMR spectra of 1\u20136 in CD2Cl2. The resonance of the cation was invariant at \u03B4 6.9 ppm (\u0394\u03BD1/20.4 kHz) whereas resonances of the titanate anions were shifting in response to the number of methyl groups (\u03B4 10.5\u20138.4 ppm (CpMe) and \u03B4 26.6\u201339.0 ppm (CpH)). The presence of toluene of crystallization in 1\u20136 was observed by 1H NMR spectra, and in the crystal structure of 6. Crystallization of 6 from tetrahydrofuran afforded solvent-free crystals of 6A. In crystal structures of both 6 and 6A the [Ti(\u03B75-C5Me5)Cl3]\u2013 titanate anion possessed shorter Ti\u2013Cg distances and longer Ti\u2013Cl bonds than the neutral species."@en . . "[5FAB3D8D1023]" . "5"^^ . . . . "000303293400016" . "Hor\u00E1\u010Dek, Michal" . . . . . "Varga, V." . "chromium; chromocenium; titanium"@en . . . . "Mach, Karel" . . . "19" . . "Pinkas, Ji\u0159\u00ED" . "Ion pairs from redox reaction of decamethylchromocene with cyclopentadienyltitanium trichlorides" . "4"^^ . . "Ion pairs from redox reaction of decamethylchromocene with cyclopentadienyltitanium trichlorides" . . . "Inorganic Chemistry Communications" . "142986" . "NL - Nizozemsko" . "10.1016/j.inoche.2012.02.003" . . "Gyepes, R." . . "Ion pairs from redox reaction of decamethylchromocene with cyclopentadienyltitanium trichlorides"@en . "MAY 2012" . "1387-7003" . "RIV/61388955:_____/12:00376246!RIV13-AV0-61388955" . "RIV/61388955:_____/12:00376246" . "P(KAN100400701), P(LC06070), V, Z(AV0Z40400503)" .