"\u010Cejka, Ji\u0159\u00ED" . . "138915" . . "179" . "High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride"@en . "2"^^ . . . "000298404600011" . "Kurfi\u0159tov\u00E1, Lenka" . "[5857E1B3F795]" . "Chang, J. - S." . "High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride" . "Hwang, Y. K." . . "P(GA104/07/0383), Z(AV0Z40400503)" . . "acylation; p-xylene; zeolites"@en . . "Catalytic behavior of metal-organic-frameworks (MOFs) Cu-3(BTC)(2), MIL-100(Fe) and MIL-100(Cr) was investigated in p-xylene acylation with benzoyl chloride and compared with the behavior of large pore zeolites Beta and USY. It has been clearly shown that MIL-100(Fe) exhibit much higher conversion of benzoyl chloride with excellent selectivity in p-xylene acylation. The performance of MIL-100(Fe) catalyst was favorable with those of other conventional heterogeneous catalysts like zeolites. Conversion of benzoyl chloride equal to 100% was achieved over MIL-100(Fe) with 20-30 min under optimized reaction conditions. It is assumed that unsaturated Lewis acid sites associated with the presence of Fe exhibit optimum acid strength for catalyzing this acylation reaction."@en . "1" . . "High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride" . "0920-5861" . "Catalysis Today" . "Seo, Y. - K." . "10.1016/j.cattod.2011.08.001" . . . . "6"^^ . "High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride"@en . "RIV/61388955:_____/12:00375913!RIV13-GA0-61388955" . . "NL - Nizozemsko" . . . . . . "5"^^ . "RIV/61388955:_____/12:00375913" . . "Catalytic behavior of metal-organic-frameworks (MOFs) Cu-3(BTC)(2), MIL-100(Fe) and MIL-100(Cr) was investigated in p-xylene acylation with benzoyl chloride and compared with the behavior of large pore zeolites Beta and USY. It has been clearly shown that MIL-100(Fe) exhibit much higher conversion of benzoyl chloride with excellent selectivity in p-xylene acylation. The performance of MIL-100(Fe) catalyst was favorable with those of other conventional heterogeneous catalysts like zeolites. Conversion of benzoyl chloride equal to 100% was achieved over MIL-100(Fe) with 20-30 min under optimized reaction conditions. It is assumed that unsaturated Lewis acid sites associated with the presence of Fe exhibit optimum acid strength for catalyzing this acylation reaction." . .