"Mutable Lewis and Bronsted Acidity of Aluminated SBA-15 as Revealed by NMR of Adsorbed Pyridine-(15)N"@en . "27" . . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . "[F2254DBD4695]" . . "Shenderovich, I, G." . "0743-7463" . "214389" . "Mutable Lewis and Bronsted Acidity of Aluminated SBA-15 as Revealed by NMR of Adsorbed Pyridine-(15)N" . . "RIV/61388955:_____/11:00365144!RIV12-GA0-61388955" . . "Zukal, Arno\u0161t" . . "5"^^ . "000295187300050" . . . "Mutable Lewis and Bronsted Acidity of Aluminated SBA-15 as Revealed by NMR of Adsorbed Pyridine-(15)N"@en . . "15N NMR; post-synthesis alumination; phase Beckmann rearrangement"@en . . . . "2"^^ . "1H and variable-temperature (15)N NMR techniques have been used to study the effect of the gradual alumination of SBA-15 on the structure and adsorption properties of this mesoporous material. The interpretation of experimental spectra suggests that aluminum chlorhydrol most effectively reacts with silica surfaces in the confinement of the cavities of rough mesopore walls, instead of forming a homogeneous aluminum film. This first leads to a gradual filling of the cavities and finally results in aluminum islands on the inner surfaces of mesopores. In the sample with a Si/Al atomic ratio of 4.1, up to half of the inner surface area of the mesopores is covered with aluminum. The alumination produces Bronsted acid sites attributed to silanol groups interacting with aluminum but does not affect the proton-donating ability of isolated silanol groups. At high Si/Al ratios, the surface contains only one type of Lewis site attributed to tetracoordinated aluminum."@en . "19" . "Rozhkova, Yu. A." . "1H and variable-temperature (15)N NMR techniques have been used to study the effect of the gradual alumination of SBA-15 on the structure and adsorption properties of this mesoporous material. The interpretation of experimental spectra suggests that aluminum chlorhydrol most effectively reacts with silica surfaces in the confinement of the cavities of rough mesopore walls, instead of forming a homogeneous aluminum film. This first leads to a gradual filling of the cavities and finally results in aluminum islands on the inner surfaces of mesopores. In the sample with a Si/Al atomic ratio of 4.1, up to half of the inner surface area of the mesopores is covered with aluminum. The alumination produces Bronsted acid sites attributed to silanol groups interacting with aluminum but does not affect the proton-donating ability of isolated silanol groups. At high Si/Al ratios, the surface contains only one type of Lewis site attributed to tetracoordinated aluminum." . . . . . "P(GA203/08/0604), P(KAN100400701), Z(AV0Z40400503)" . . . "RIV/61388955:_____/11:00365144" . "Gurinov, A. A." . "10.1021/la2017566" . "\u010Cejka, Ji\u0159\u00ED" . . "Mutable Lewis and Bronsted Acidity of Aluminated SBA-15 as Revealed by NMR of Adsorbed Pyridine-(15)N" . . . "Langmuir" . "9"^^ .