"205560" . . "Intramolecular activation of pendant alkenyl group as a tool for modification of the zirconocene framework" . . "The diphenyl zirconocene [(eta(5)-C(5)H(5)){eta(5)-C(5)H(4)CMe(2)(CH(2))(2)CH=CH(2)}ZrPh(2)] (2) was readily obtained from the corresponding zirconocene dichloride 1 and two equivalents of phenyllithium. Upon thermal treatment at 80 degrees C, complex 2 released benzene, with concomitant activation of the pendant double bond and formation of intramolecularly alpha-tethered zirconaindane [(eta(5)-C(5)H(5)){eta(5), eta(1), eta(1)-C(5)H(4)CMe(2)(CH(2))(2)CHCH(2)C(6)H(4)}Zr] (3). Both Zr-C sigma-bonds in 3 easily undergo nucleophilic reactions with two equivalents of HCl or one equivalent of Cl(2)PPh giving rise to zirconocene dichlorides with pendant phenyl group [(eta(5)-C(5)H(5)){eta(5)-C(5)H(4)CMe(2)(CH(2))(4)Ph}ZrCl(2)] (4) or with 1-phenylphosphindolinyl moiety [(eta(5)-C(5)H(5)){eta(5)-C(5)H(4)CMe(2)(CH(2))(2)cyclo-CHCH(2)C(6)H(4)P(Ph)}ZrCl(2)] (5), respectively."@en . . "4"^^ . . "Inorganica chimica acta" . "Kubi\u0161ta, Ji\u0159\u00ED" . . "The diphenyl zirconocene [(eta(5)-C(5)H(5)){eta(5)-C(5)H(4)CMe(2)(CH(2))(2)CH=CH(2)}ZrPh(2)] (2) was readily obtained from the corresponding zirconocene dichloride 1 and two equivalents of phenyllithium. Upon thermal treatment at 80 degrees C, complex 2 released benzene, with concomitant activation of the pendant double bond and formation of intramolecularly alpha-tethered zirconaindane [(eta(5)-C(5)H(5)){eta(5), eta(1), eta(1)-C(5)H(4)CMe(2)(CH(2))(2)CHCH(2)C(6)H(4)}Zr] (3). Both Zr-C sigma-bonds in 3 easily undergo nucleophilic reactions with two equivalents of HCl or one equivalent of Cl(2)PPh giving rise to zirconocene dichlorides with pendant phenyl group [(eta(5)-C(5)H(5)){eta(5)-C(5)H(4)CMe(2)(CH(2))(4)Ph}ZrCl(2)] (4) or with 1-phenylphosphindolinyl moiety [(eta(5)-C(5)H(5)){eta(5)-C(5)H(4)CMe(2)(CH(2))(2)cyclo-CHCH(2)C(6)H(4)P(Ph)}ZrCl(2)] (5), respectively." . "P(GA203/09/1574), P(GPP207/10/P200), P(LC06070), Z(AV0Z40400503)" . "Pinkas, Ji\u0159\u00ED" . . "[06E766BAE97B]" . . "NL - Nizozemsko" . . . . . . "373" . ",etallocenes; zirconium; benzyne complexes"@en . . "RIV/61388955:_____/11:00361646!RIV12-GA0-61388955" . "Hor\u00E1\u010Dek, Michal" . "4"^^ . "Lama\u010D, Martin" . . . . "4"^^ . "0020-1693" . . . . "RIV/61388955:_____/11:00361646" . "Intramolecular activation of pendant alkenyl group as a tool for modification of the zirconocene framework"@en . . . "10.1016/j.ica.2011.03.061" . "1" . "Intramolecular activation of pendant alkenyl group as a tool for modification of the zirconocene framework"@en . "Intramolecular activation of pendant alkenyl group as a tool for modification of the zirconocene framework" . . . "000291244600043" .