"374" . . "Linseis, M." . . . . . "RIV/61388955:_____/11:00361465" . "NL - Nizozemsko" . "ruthenium; vinyl complexes; electrochemistry"@en . "10.1016/j.ica.2011.03.071" . . . . "Z\u00E1li\u0161, Stanislav" . "[2B921D9D7F57]" . "4"^^ . . "RIV/61388955:_____/11:00361465!RIV12-AV0-61388955" . "1"^^ . . . "1" . . . "M\u00FCcke, P." . "Inorganica chimica acta" . "Vinyl-ruthenium entities as markers for intramolecular electron transfer processes"@en . "0020-1693" . "Winter, R. F." . "P(KAN100400702), P(LD11086), Z(AV0Z40400503)" . "The present account summarizes our work on mononuclear vinyl ruthenium complexes of the type RuCl(CH=CH')(CO)(PR(3))(2)L, divinyl-bridged diruthenium complexes {RuCl(CO)(PR(3))(2)L}(2)(l-CH=CHbridge-CH=CH) and on heterobinuclear systems where only one of the two redox-active metal-organic moieties is of the vinyl ruthenium type. The favourable electrochemical properties of the {RuCl( CO)(PR(3))(2)L(CH=CH-) tag and the various spectroscopic handles offered by that unit provide detailed insights into the charge and spin delocalization over the {MCl(CO)(PR(3))(2)L} and CH=CHR' constituents in their associated radical cations. They also offer a convenient means for measuring electronic coupling in the mixed-valent radical cations of the homo-and heterodinuclear vinyl-bridged complexes and, under favourable circumstances, on the rate of intramolecular electron transfer between the individual redox sites."@en . . . . "Vinyl-ruthenium entities as markers for intramolecular electron transfer processes" . "Vinyl-ruthenium entities as markers for intramolecular electron transfer processes"@en . . . . "The present account summarizes our work on mononuclear vinyl ruthenium complexes of the type RuCl(CH=CH')(CO)(PR(3))(2)L, divinyl-bridged diruthenium complexes {RuCl(CO)(PR(3))(2)L}(2)(l-CH=CHbridge-CH=CH) and on heterobinuclear systems where only one of the two redox-active metal-organic moieties is of the vinyl ruthenium type. The favourable electrochemical properties of the {RuCl( CO)(PR(3))(2)L(CH=CH-) tag and the various spectroscopic handles offered by that unit provide detailed insights into the charge and spin delocalization over the {MCl(CO)(PR(3))(2)L} and CH=CHR' constituents in their associated radical cations. They also offer a convenient means for measuring electronic coupling in the mixed-valent radical cations of the homo-and heterodinuclear vinyl-bridged complexes and, under favourable circumstances, on the rate of intramolecular electron transfer between the individual redox sites." . "000292962900006" . "Vinyl-ruthenium entities as markers for intramolecular electron transfer processes" . "238463" . "16"^^ .