. "29" . . . "The ansa-1,2-bis(dimethylsilylene)ethane chain is exclusively activated when the parent ansa-permethyltitanocene compounds are reduced to titanium(II) either by thermolysis of titanium-methyl bonds or by the reduction of the parent titanocene dichloride ansa-[TiCl2(eta(5)-CH2Me2-SiC5Me4)(2)] (8) with magnesium. The compound [Ti(eta(2):eta(5):eta(5)-C5Me4SiMe2CH=CHSiMe2C5Me4)] (10), with the double bond back-bonded to titanium(II), is formed by thermolysis of ansa-[TiMe2(eta(5)-CH2Me2SiC5Me4)(2)] (9) with elimination of methane or by hydrogen transfer from the ansa-chain to easily leaving ethene or 1,4-bis(trimethylsilyl)buta-1,3-diyne pi-coordinated to an ansa-titanocene moiety. The paramagnetic compound ansa-[Ti-III{eta(1):eta(5):eta(5)-C5Me4SiMe2CHCH2SiMe2C5Me4}] (12), with the anso-chain tethered to titanium, arises from demethanation of transiently formed ansa-[(TiMe)-Me-III(eta(5)-CH2Me2SiC5Me4)(2)] or by the reduction of 8 with magnesium in tetrahydrofuran." . . "RIV/61388955:_____/10:00351877!RIV11-MSM-61388955" . . "Reduction-Induced Exclusive Activation of the ansa-1,2-Bis(dimethylsilylene)ethane Chain in ansa-Permethyltitanocene Compounds" . "Mach, Karel" . . "Hor\u00E1\u010Dek, Michal" . "0276-7333" . . . "7"^^ . "000283572100065" . "P(IAA400400708), P(LC06070), Z(AV0Z40400503), Z(MSM0021620857)" . . . . . "21" . "10"^^ . "Reduction-Induced Exclusive Activation of the ansa-1,2-Bis(dimethylsilylene)ethane Chain in ansa-Permethyltitanocene Compounds"@en . . "5"^^ . . "RIV/61388955:_____/10:00351877" . "The ansa-1,2-bis(dimethylsilylene)ethane chain is exclusively activated when the parent ansa-permethyltitanocene compounds are reduced to titanium(II) either by thermolysis of titanium-methyl bonds or by the reduction of the parent titanocene dichloride ansa-[TiCl2(eta(5)-CH2Me2-SiC5Me4)(2)] (8) with magnesium. The compound [Ti(eta(2):eta(5):eta(5)-C5Me4SiMe2CH=CHSiMe2C5Me4)] (10), with the double bond back-bonded to titanium(II), is formed by thermolysis of ansa-[TiMe2(eta(5)-CH2Me2SiC5Me4)(2)] (9) with elimination of methane or by hydrogen transfer from the ansa-chain to easily leaving ethene or 1,4-bis(trimethylsilyl)buta-1,3-diyne pi-coordinated to an ansa-titanocene moiety. The paramagnetic compound ansa-[Ti-III{eta(1):eta(5):eta(5)-C5Me4SiMe2CHCH2SiMe2C5Me4}] (12), with the anso-chain tethered to titanium, arises from demethanation of transiently formed ansa-[(TiMe)-Me-III(eta(5)-CH2Me2SiC5Me4)(2)] or by the reduction of 8 with magnesium in tetrahydrofuran."@en . . "284309" . "Kubi\u0161ta, Ji\u0159\u00ED" . "C\u00EDsa\u0159ov\u00E1, I." . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . . "Reduction-Induced Exclusive Activation of the ansa-1,2-Bis(dimethylsilylene)ethane Chain in ansa-Permethyltitanocene Compounds"@en . "Gyepes, R." . . . "Organometallics" . "Luke\u0161ov\u00E1, Lenka" . . "Pinkas, Ji\u0159\u00ED" . "Reduction-Induced Exclusive Activation of the ansa-1,2-Bis(dimethylsilylene)ethane Chain in ansa-Permethyltitanocene Compounds" . "ansa-1,2-bis(dimethylsilylene)ethane; ansa-permethyltitanocene; titanium"@en . . . . "[E418B3FB2276]" . . .