. "Large-scale plasma was created in gas mixtures containing carbon monoxide by high-power laser-induced dielectric breakdown (LIDB). The composition of the mixtures used corresponded to a cometary and/or meteoritic impact into the Earth\u2019s early atmosphere. A multiple-centimeter-sized fireball was created by focusing a single 85 J, 450 ps near-infrared laser pulse into the center of a 15 L gas cell. The excited reaction intermediates that formed in various stages of the LIDB plasma chemical evolution were investigated by optical emission spectroscopy (OES) with temporal resolution. Special attention was paid to any OES signs of molecular ions. However, carbon monoxide cations were registered only if their production was enhanced by Penning ionization, i.e., excess He was added to the CO. The chemical consequences of laser-produced plasma generation in a CO-N2-H2O mixture were investigated using high resolution Fourier-transform infrared absorption spectroscopy and gas chromatography." . "RIV/61388955:_____/08:00318732!RIV09-AV0-61388955" . . "31" . "organic compounds; emission spectroscopy; nitrogen fixation"@en . "Spectroscopic Investigations of High-Power Laser-Induced Dielectric Breakdown in Gas Mixtures Containing Carbon Monoxide"@en . "1089-5639" . . . "5"^^ . . . "P(GA203/06/1278), P(LC528), Z(AV0Z10100523), Z(AV0Z40400503)" . "Spectroscopic Investigations of High-Power Laser-Induced Dielectric Breakdown in Gas Mixtures Containing Carbon Monoxide"@en . . "Velkoobjemov\u00E1 plasma byla produkov\u00E1na ve sm\u011Bsi plyn\u016F obsahuj\u00EDc\u00EDch CO pomoc\u00ED vysokoenergetick\u00E9ho laserem indukovan\u00E9ho dielektrick\u00E9ho pr\u016Frazu. Slo\u017Een\u00ED pou\u017Eit\u00FDch sm\u011Bs\u00ED bylo voleno tak, aby co nejl\u00E9pe odpov\u00EDdalo slo\u017Een\u00ED praatmosf\u00E9ry Zem\u011B a experiment simuloval komet\u00E1rn\u00ED a meteorick\u00E9 dopady. N\u011Bkolika centimetrov\u00E1 plazmov\u00E1 jiskra byla tvo\u0159ena fokusac\u00ED bl\u00EDzk\u00E9ho-infra\u010Derven\u00E9ho laserov\u00E9ho pulsu o energii 85 J a d\u00E9lce 450 ps do st\u0159edu 15 l sklen\u011Bn\u00E9 kyvety. Optickou emisn\u00ED spektroskopi\u00ED s \u010Dasov\u00FDm rozli\u0161en\u00EDm byly identifikov\u00E1ny \u010D\u00E1stice v r\u016Fzn\u00FDch stavech chemick\u00E9ho v\u00FDvoje LIDB plazmy vznikl\u00E9 excita\u010Dn\u00EDmi reakcemi. Velk\u00E1 pozornost byla v\u011Bnov\u00E1na OES sign\u00E1l\u016Fm molekul\u00E1rn\u00EDch iont\u016F. Jednou kladn\u011B nabit\u00E1 molekula oxidu uhelnat\u00E9ho byla pozorov\u00E1na pouze jako produkt Penningovy ionizace (p\u0159\u00EDdavek He k CO). Chemick\u00FD v\u00FDvoj laserem vybuzen\u00E9ho plazmatu ve sm\u011Bsi CO-N2-H2O byl sledov\u00E1n tak\u00E9 pomoc\u00ED vysoce rozli\u0161en\u00E9 infra\u010Derven\u00E9 absorp\u010Dn\u00ED spektroskopie s Fourierovou transformac\u00ED a plynovou chromatografi\u00ED."@cs . . "Journal of Physical Chemistry A" . "Civi\u0161, Svatopluk" . . . . "112" . "4"^^ . . "Large-scale plasma was created in gas mixtures containing carbon monoxide by high-power laser-induced dielectric breakdown (LIDB). The composition of the mixtures used corresponded to a cometary and/or meteoritic impact into the Earth\u2019s early atmosphere. A multiple-centimeter-sized fireball was created by focusing a single 85 J, 450 ps near-infrared laser pulse into the center of a 15 L gas cell. The excited reaction intermediates that formed in various stages of the LIDB plasma chemical evolution were investigated by optical emission spectroscopy (OES) with temporal resolution. Special attention was paid to any OES signs of molecular ions. However, carbon monoxide cations were registered only if their production was enhanced by Penning ionization, i.e., excess He was added to the CO. The chemical consequences of laser-produced plasma generation in a CO-N2-H2O mixture were investigated using high resolution Fourier-transform infrared absorption spectroscopy and gas chromatography."@en . "[ED337FB29B44]" . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . . . . . . "000258097800006" . . "Spektroskopick\u00E1 studie \u010D\u00E1stic vznikaj\u00EDc\u00EDch po vysokoenergetick\u00E9m laserem indukovan\u00E9m dielektrick\u00E9m pr\u016Frazu v plynn\u00FDch sm\u011Bs\u00ED obsahuj\u00EDc\u00EDch oxid uhelnat\u00FD"@cs . . "Spektroskopick\u00E1 studie \u010D\u00E1stic vznikaj\u00EDc\u00EDch po vysokoenergetick\u00E9m laserem indukovan\u00E9m dielektrick\u00E9m pr\u016Frazu v plynn\u00FDch sm\u011Bs\u00ED obsahuj\u00EDc\u00EDch oxid uhelnat\u00FD"@cs . "Juha, Libor" . "Cihelka, Jaroslav" . "RIV/61388955:_____/08:00318732" . . . "Spectroscopic Investigations of High-Power Laser-Induced Dielectric Breakdown in Gas Mixtures Containing Carbon Monoxide" . "Spectroscopic Investigations of High-Power Laser-Induced Dielectric Breakdown in Gas Mixtures Containing Carbon Monoxide" . "8"^^ . "396465" . . "Sazama, Petr" . "Bab\u00E1nkov\u00E1, Dagmar" .