"386507" . "Demel, Jan" . . "amides; phosphines; PAMAM"@en . "1381-1169" . "7"^^ . "NL - Nizozemsko" . . "1"^^ . . "Lama\u010D, M." . "1\u00B4-(Difenylfosfino)-1-(N-butylcarbamoyl)ferocen (P1) a analogick\u00E9 vy\u017E\u0161\u00ED amidy P2\u20134 odvozen\u00E9 od prvn\u00ED generace PAMAM dendrimer\u016F, kter\u00E9 nesou a\u017E \u010Dty\u0159i 1\u00B4-(difenylfosfino)ferocen-1-yl skupiny, byly p\u0159ipraveny amidac\u00ED (poly)amin\u016F pomoc\u00ED 1\u00B4-(difenylfosfino)ferocenekarboxylov\u00E9 kyseliny (Hdpf). Testov\u00E1n\u00ED amid\u016F P1\u20134 jako ligand\u016F pro palladiem katalyzovan\u00E9 Suzukiho a Heck\u016Fv coupling-reakce uk\u00E1zalo, \u017Ee tyto amidofosfiny si zachov\u00E1van\u00ED aktivitu jednotliv\u00FDch fosfinoferocenov\u00FDch jednotek. I pro takto pom\u011Brn\u011B mal\u00E9 syst\u00E9my byl pozorov\u00E1n pozitivn\u00ED dendrimerov\u00FD efekt, slou\u010Deniny nesouc\u00ED v\u011Bt\u0161\u00ED po\u010Det fosfinoferocenov\u00FDch skupin reagovaly rychleji p\u0159i zachov\u00E1n\u00ED stejn\u00E9ho obsahu palladia v syst\u00E9mu a pom\u011Bru P k Pd."@cs . "Phosphinoferrocenyl-terminated amidoamines: Synthesis and catalytic utilization in palladium-mediated C\u2013C bond forming reactions" . "Lang, H." . . . "Phosphinoferrocenyl-terminated amidoamines: Synthesis and catalytic utilization in palladium-mediated C\u2013C bond forming reactions"@en . . "Phosphinoferrocenyl-terminated amidoamines: Synthesis and catalytic utilization in palladium-mediated C\u2013C bond forming reactions"@en . "K\u00FChnert, J." . . "1\u00B4-(Diphenylphosphino)-1-(N-butylcarbamoyl)ferrocene (P1) and the analogous higher amides P2\u20134 related to the first-generation PAMAM dendrimers bearing up to four 1\u00B4-(diphenylphosphino)ferrocen-1-yl terminal groups were synthesized by amidation of the respective (poly)amines with 1\u00B4-(diphenylphosphino)ferrocenecarboxylic acid (Hdpf). Testing of amides P1\u20134 as ligands for palladium-catalyzed Suzuki and Heck coupling reactions has shown that these amidophosphines preserve the activity of the single phosphinoferrocenyl unit, giving rise to active catalysts in both C\u2013C forming reactions. Even for such relatively small systems, a positive influence of the dendritic assembly was notable as the compounds bearing a higher number of the phosphinoferrocenyl termini afforded faster reacting catalytic systems at the same palladium loading and P-to-Pd ratio."@en . . "Fosfinoferocen-zakon\u010Den\u00E9 amidoaminy: Synt\u00E9za a pou\u017Eit\u00ED v palladiem katalyzovan\u00FDch reakc\u00EDch se vznikem C\u2013C vazby"@cs . . "1-2" . "1\u00B4-(Diphenylphosphino)-1-(N-butylcarbamoyl)ferrocene (P1) and the analogous higher amides P2\u20134 related to the first-generation PAMAM dendrimers bearing up to four 1\u00B4-(diphenylphosphino)ferrocen-1-yl terminal groups were synthesized by amidation of the respective (poly)amines with 1\u00B4-(diphenylphosphino)ferrocenecarboxylic acid (Hdpf). Testing of amides P1\u20134 as ligands for palladium-catalyzed Suzuki and Heck coupling reactions has shown that these amidophosphines preserve the activity of the single phosphinoferrocenyl unit, giving rise to active catalysts in both C\u2013C forming reactions. Even for such relatively small systems, a positive influence of the dendritic assembly was notable as the compounds bearing a higher number of the phosphinoferrocenyl termini afforded faster reacting catalytic systems at the same palladium loading and P-to-Pd ratio." . . . "000256178900006" . "Fosfinoferocen-zakon\u010Den\u00E9 amidoaminy: Synt\u00E9za a pou\u017Eit\u00ED v palladiem katalyzovan\u00FDch reakc\u00EDch se vznikem C\u2013C vazby"@cs . . . . "\u0160t\u011Bpni\u010Dka, P." . "RIV/61388955:_____/08:00315305!RIV09-AV0-61388955" . "[F6BE4F9D94A1]" . "Phosphinoferrocenyl-terminated amidoamines: Synthesis and catalytic utilization in palladium-mediated C\u2013C bond forming reactions" . "6"^^ . "Nicolai, A." . . . "RIV/61388955:_____/08:00315305" . "P(GA104/05/0192), P(LC06070), Z(AV0Z40400503), Z(MSM0021620857)" . "285" . . "Journal of Molecular Catalysis A-Chemical" . . .