"Sarkar, B." . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . "A series of metal complexes with the non-innocent N,N\u2019-Bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure" . "A series of metal complexes with the non-innocent N,N\u2019-Bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure"@en . "\u0158ada homoleptick\u00FDch komplex\u016F s non-innocent ligandy odvozen\u00FDch od N,N' -bis(pentafluorofenyl)-o-fenylenediamine (H2Fpda) je pops\u00E1na. [NiII(Fsbqdi)2] (1), [PdII(Fsbqdi)2] (2), [CoII(Fsbqdi)2] (3), a [CuII(Fsbqdi)2] (4) byl syntetizov\u00E1ny, kde (Fsbqdi)1- reprezentuje radik\u00E1lov\u00FD anion vytvo\u0159en\u00FD jednoelektronovou oxidac\u00ED dvojn\u00E1sobn\u011B deprotonovan\u00E9ho H2Fpda. Komplex 4 je prvn\u00ED CuII komplex, kde oba o-fenylenediaminov\u00E9 ligandy jsou monoanionick\u00FDmi radik\u00E1ly. Elektronov\u00E9 struktury neutr\u00E1ln\u00EDch slou\u010Denin 1-4 a n\u011Bkter\u00FDch jejich kationick\u00FDch a anionick\u00FDch redox stav\u016F byly prov\u011B\u0159eny s pou\u017Eit\u00EDm EPR a UV-VIS-NIR spektroelektrochemie. Zkroucen\u00E1 geometrie komplex\u016F zp\u016Fsobuje zna\u010Dn\u00E9 zm\u011Bny v jejich elektronov\u00FDch struktur\u00E1ch ve srovn\u00E1n\u00ED se zn\u00E1m\u00FDmi \u010Dtvercov\u011B-plan\u00E1rn\u00EDmi komplexy."@cs . . "A series of metal complexes with the non-innocent N,N\u2019-Bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure" . . . "Fiedler, Jan" . "P(OC 139), P(OC 140), Z(AV0Z40400503)" . . "metal complexes; non-innocent N,N\u2019-Bis(pentafluorophenyl)-o-phenylenediamido ligand; electronic structure"@en . "Burghaus, O." . . . . "1"^^ . . . "RIV/61388955:_____/08:00315010!RIV09-AV0-61388955" . "-" . "354491" . . "10" . . "Duboc, C." . "9"^^ . "Kaim, W." . . "1477-9226" . "Khusniyarov, M. M." . . "RIV/61388955:_____/08:00315010" . "Dalton Transactions" . . "11"^^ . . "\u0158ada kovov\u00FDch komplex\u016F s non-innocent ligandem N,N'-Bis(pentafluorofenyl)-o-fenylendiamido: nastaven\u00ED elektronov\u00E9 struktury vlivem zkroucen\u00E9 geometrie"@cs . "van Slageren, J." . "Harms, K." . "[DB28372E9F32]" . "A series of metal complexes with the non-innocent N,N\u2019-Bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure"@en . "A series of homoleptic complexes with non-innocent ligands derived from N,N\u2019 -bis(pentafluorophenyl)-o-phenylenediamine (H2Fpda) are reported. [NiII(Fsbqdi)2] (1), [PdII(Fsbqdi)2] (2), [CoII(Fsbqdi)2] (3), and [CuII(Fsbqdi)2] (4) were synthesized, where (Fsbqdi)1- represents a radical anion formed by one-electron oxidation of the doubly deprotonated H2Fpda. Complex 4 is the first CuII complex where both o-phenylenediamine derived ligands are monoanionic radicals. The electronic structures of the neutral compounds 1-4 and of some of their cationic and/or anionic neighboring redox states were probed using EPR and UV-VIS-NIR spectroelectrochemistry. The twisted geometry of the complexes results in considerable changes in their electronic structures compared to the well known square-planar complexes."@en . "\u0158ada kovov\u00FDch komplex\u016F s non-innocent ligandem N,N'-Bis(pentafluorofenyl)-o-fenylendiamido: nastaven\u00ED elektronov\u00E9 struktury vlivem zkroucen\u00E9 geometrie"@cs . . . "Sundermayer, J." . . "A series of homoleptic complexes with non-innocent ligands derived from N,N\u2019 -bis(pentafluorophenyl)-o-phenylenediamine (H2Fpda) are reported. [NiII(Fsbqdi)2] (1), [PdII(Fsbqdi)2] (2), [CoII(Fsbqdi)2] (3), and [CuII(Fsbqdi)2] (4) were synthesized, where (Fsbqdi)1- represents a radical anion formed by one-electron oxidation of the doubly deprotonated H2Fpda. Complex 4 is the first CuII complex where both o-phenylenediamine derived ligands are monoanionic radicals. The electronic structures of the neutral compounds 1-4 and of some of their cationic and/or anionic neighboring redox states were probed using EPR and UV-VIS-NIR spectroelectrochemistry. The twisted geometry of the complexes results in considerable changes in their electronic structures compared to the well known square-planar complexes." . .