. "1" . "The use of differential pulse anodic stripping voltammetry and diffusive gradient in thin films for heavy metals speciation in soil solution" . "1"^^ . "RIV/61388955:_____/08:00309841" . "PL - Polsk\u00E1 republika" . "Central European Journal of Chemistry" . . . "Miholov\u00E1, D." . . "401744" . . "Aplikace diferen\u010Dn\u00ED pulsn\u00ED anodick\u00E9 rozpou\u0161t\u011Bc\u00ED voltametrie a difusn\u00EDho gradientu na tenk\u00E9 vrstv\u011B pro speciaci t\u011B\u017Ek\u00FDch kov\u016F v p\u016Fdn\u00EDm roztoku"@cs . . "6" . . "In the soil solutions obtained in situ with suction cups from soils (Cambisol and Fluvisol) of pot experiment with Salix smithiana Smith, Lolium perenne L. and Thlaspi caerulescens J. & C. Presl heavy metals species (Cd, Pb and Cu) were assayed by differential pulse anodic stripping voltammetry and diffusive gradient in thin films. Prediction of accumulation performed best at free metal ion concentrations in unchanged pH (in 10(-3) mol L-1 NaClO4 base electrolyte). The speciation provided by differential pulse anodic stripping voltammetry according to pH can provide a detailed description of the soil solution matrix. The concentration of free metals in unchanged pH represents a small part of the total content and varied from 0.04 to 0.75% with two exceptions found for accumulating plants (the content of Cd2+ in the soil solution from T. caerulescens was about 6% and the content of Cu2+ in the soil solution from S. smithiana was about 30%)."@en . . . "Tlusto\u0161, P." . "6"^^ . "\u0160est\u00E1kov\u00E1, Ivana" . "The use of differential pulse anodic stripping voltammetry and diffusive gradient in thin films for heavy metals speciation in soil solution" . "The use of differential pulse anodic stripping voltammetry and diffusive gradient in thin films for heavy metals speciation in soil solution"@en . . "In the soil solutions obtained in situ with suction cups from soils (Cambisol and Fluvisol) of pot experiment with Salix smithiana Smith, Lolium perenne L. and Thlaspi caerulescens J. & C. Presl heavy metals species (Cd, Pb and Cu) were assayed by differential pulse anodic stripping voltammetry and diffusive gradient in thin films. Prediction of accumulation performed best at free metal ion concentrations in unchanged pH (in 10(-3) mol L-1 NaClO4 base electrolyte). The speciation provided by differential pulse anodic stripping voltammetry according to pH can provide a detailed description of the soil solution matrix. The concentration of free metals in unchanged pH represents a small part of the total content and varied from 0.04 to 0.75% with two exceptions found for accumulating plants (the content of Cd2+ in the soil solution from T. caerulescens was about 6% and the content of Cu2+ in the soil solution from S. smithiana was about 30%)." . . "Sz\u00E1kov\u00E1, J." . "000252467300010" . . . . "V p\u016Fdn\u00EDch roztoc\u00EDch, z\u00EDsk\u00E1van\u00FDch in situ pomoc\u00ED p\u016Fdn\u00ED sondy z p\u016Fd (Cambisol a Fluvisol) v n\u00E1dobov\u00E9m experimentu, kde byly p\u011Bstov\u00E1ny Salix smihiana Smith, Lolium perenne L. a Thlaspi caerulescens J.& C. Presl byly stanovov\u00E1ny specie t\u011B\u017Ek\u00FDch kov\u016F (Cd, Pb a Cu) pomoc\u00ED diferen\u010Dn\u00ED pulsn\u00ED anodick\u00E9 rozpou\u0161t\u011Bc\u00ED voltametrie a difusn\u00EDho gradientu na tenk\u00E9 vrstv\u011B. Pro progn\u00F3zu akumulace rostlinami je nejvhodn\u011Bj\u0161\u00ED koncentrace voln\u00FDch iont\u016F kov\u016F v p\u016Fdn\u00EDm roztoku p\u0159i nezm\u011Bn\u011Bn\u00E9m pH (v z\u00E1kladn\u00EDm elektrolytu 1x l0-3 mol L-1 NaClO4 ). Speciace diferen\u010Dn\u00ED pulsn\u00ED anodickou rozpou\u0161t\u011Bc\u00ED voltametri\u00ED v z\u00E1vislosti na pH umo\u017E\u0148uje detaln\u011Bj\u0161\u00ED popis p\u016Fdn\u00EDho roztoku. Koncentrace kov\u016F ve form\u011B voln\u00FDch iont\u016F p\u0159i nezm\u011Bn\u011Bn\u00E9m pH odpov\u00EDd\u00E1 pouze mal\u00E9 \u010D\u00E1sti celkov\u00E9ho obsahu a to od 0.04 do 0.75 % se dv\u011Bma v\u00FDjimkami nalezen\u00FDmi u akumuluj\u00EDc\u00EDch rostlin (obsah Cd2+ v p\u016Fdn\u00EDm roztoku od T. caerulescens byl cca 6% a obsah Cu2+ v p\u016Fdn\u00EDm roztoku od S.Smithiana byl cca 30%)."@cs . "Aplikace diferen\u010Dn\u00ED pulsn\u00ED anodick\u00E9 rozpou\u0161t\u011Bc\u00ED voltametrie a difusn\u00EDho gradientu na tenk\u00E9 vrstv\u011B pro speciaci t\u011B\u017Ek\u00FDch kov\u016F v p\u016Fdn\u00EDm roztoku"@cs . "RIV/61388955:_____/08:00309841!RIV09-AV0-61388955" . "Jakl, M." . "heavy metals; soil solution; speciation"@en . . . "P(GA521/06/0496), Z(AV0Z40400503), Z(MSM6046070901)" . "Jaklov\u00E1 Dytrtov\u00E1, J." . "The use of differential pulse anodic stripping voltammetry and diffusive gradient in thin films for heavy metals speciation in soil solution"@en . "[01EEBB4C8A33]" . . . "9"^^ . "1895-1066" .