"Vradman, L." . "5"^^ . . . "The kinetic model of the reduction of NO to N2 with decane, developed based on the experimental data over Fe-MFI catalyst, has been applied for the oxidation of NO to NO2 and reduction of NO2 to N2 with decane over Cu-MFI catalyst. The model fits well the experimental data of oxidation of NO as well as reduction of NO to N2. Remarkable differences have been found in performance of Cu-MFI and Fe-MFI catalysts. While Fe-MFI is more active in oxidation of NO to NO2, Cu-MFI exhibits much higher activity in the reduction of NO with decane. The kinetic model indicates that the significantly lower activity of Fe-MFI in comparison with Cu-MFI in transformation of NOx to nitrogen is due to higher rate of transformation of NO2, formed in the first step by the oxidation of NO, back to NO instead to molecular nitrogen." . "[F3E5A1EB1820]" . "8"^^ . "Kinetic experiments and modeling of NO oxidation and SCR of NOx with decane over Cu- and Fe-MFI catalysts"@en . . . "Martens, J. A." . "Kinetick\u00FD model redukce NO na N2 dekanem vyvinut\u00FD na z\u00E1klad\u011B experiment\u00E1ln\u00EDch dat z\u00EDskan\u00FDch na Fe-MFI katalzy\u00E1toru byl aplikov\u00E1n na oxidaci NO na NO2 a redukci NO2 na N2 s dekanem na Cu-MFI katalyz\u00E1toru. Ve funkci Cu-MFI a Fe-MFI katalyz\u00E1tor\u016F byly nalezeny v\u00FDznamn\u00E9 rozd\u00EDly. Fe-MFI katalyz\u00E1tor je v\u00EDce aktivn\u00ED v oxidaci NO na NO2, zat\u00EDmco Cu-MFI katalyz\u00E1tor vykazuje mnohem v\u011Bt\u0161\u00ED aktivitu v redukci NO na N2. Kinetick\u00FD model indikuje, \u017Ee signifikantn\u011B ni\u017E\u0161\u00ED aktivita Fe-MFI v transformaci NOx na dus\u00EDk ve srovn\u00E1n\u00ED s Cu-MFI je zap\u0159\u00ED\u010Din\u011Bna vy\u0161\u0161\u00ED rychlost\u00ED transformace NO2, vznikaj\u00EDc\u00EDm v prvn\u00EDm kroku oxidac\u00ED NO, zp\u011Bt na NO nam\u00EDsto molekul\u00E1rn\u00EDho dus\u00EDku."@cs . "Applied Catalysis. B - Environmental" . "70" . . "Brosius, R." . . . "O, Z(AV0Z40400503)" . "RIV/61388955:_____/07:00099368!RIV08-AV0-61388955" . "RIV/61388955:_____/07:00099368" . "Sazama, Petr" . . "429040" . "Kinetick\u00E9 experimenty a modelov\u00E1n\u00ED oxidace NO a SCR-NOx s dekanem na Cu- a Fe-MFI katalyz\u00E1torech"@cs . "Zukerman, R." . "Wichterlov\u00E1, Blanka" . "3"^^ . . . "0926-3373" . . "\u010Capek, Libor" . . "Kinetic experiments and modeling of NO oxidation and SCR of NOx with decane over Cu- and Fe-MFI catalysts" . . "The kinetic model of the reduction of NO to N2 with decane, developed based on the experimental data over Fe-MFI catalyst, has been applied for the oxidation of NO to NO2 and reduction of NO2 to N2 with decane over Cu-MFI catalyst. The model fits well the experimental data of oxidation of NO as well as reduction of NO to N2. Remarkable differences have been found in performance of Cu-MFI and Fe-MFI catalysts. While Fe-MFI is more active in oxidation of NO to NO2, Cu-MFI exhibits much higher activity in the reduction of NO with decane. The kinetic model indicates that the significantly lower activity of Fe-MFI in comparison with Cu-MFI in transformation of NOx to nitrogen is due to higher rate of transformation of NO2, formed in the first step by the oxidation of NO, back to NO instead to molecular nitrogen."@en . . . . . "Kinetic experiments and modeling of NO oxidation and SCR of NOx with decane over Cu- and Fe-MFI catalysts"@en . . "Kinetick\u00E9 experimenty a modelov\u00E1n\u00ED oxidace NO a SCR-NOx s dekanem na Cu- a Fe-MFI katalyz\u00E1torech"@cs . "Herskowitz, M." . "Kinetic experiments and modeling of NO oxidation and SCR of NOx with decane over Cu- and Fe-MFI catalysts" . "NO oxidation; Nox reduction with hydrocarbons; heterogeneous kinetics; iron zeolite"@en . . "NL - Nizozemsko" . "53;57" . "1-4" .