"Wark, M." . . . "19" . . . . "Marschall, R." . . "P\u0159\u00EDprava uspo\u0159\u00E1dan\u00FDch funkcionalizovan\u00FDch silikov\u00FDch materi\u00E1l\u016F s vysokou protonovou vodivost\u00ED pomoc\u00ED mikrovlnn\u00E9 techniky"@cs . . . "RIV/61388955:_____/07:00093586!RIV08-MSM-61388955" . "A simple and fast method for the preparation of the Si-MCM-41 functionalized with sulfonic acid groups (SO3H) was developed. It is based on a co-condensation synthesis and microwave treatment, which ensures an effective removal of the template (cetyltrimethylammonium bromide) and the simultaneous oxidation of thiols to SO3H groups. The obtained hybrid materials exhibit a very high proton conductivity of up to 0.2 S/cm at 100% relative humidity, which increases continuously with the temperature. The coverage of the MCM-41 pore walls with the propyl chains bearing the SO3H groups is so high that more than one SO3H group is present per nm2 of the inner surface."@en . "Ordered Functionalized Silica Materials with High Proton Conductivity"@en . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . "0897-4756" . . "Rathousk\u00FD, Ji\u0159\u00ED" . "A simple and fast method for the preparation of the Si-MCM-41 functionalized with sulfonic acid groups (SO3H) was developed. It is based on a co-condensation synthesis and microwave treatment, which ensures an effective removal of the template (cetyltrimethylammonium bromide) and the simultaneous oxidation of thiols to SO3H groups. The obtained hybrid materials exhibit a very high proton conductivity of up to 0.2 S/cm at 100% relative humidity, which increases continuously with the temperature. The coverage of the MCM-41 pore walls with the propyl chains bearing the SO3H groups is so high that more than one SO3H group is present per nm2 of the inner surface." . "7"^^ . . . "6401;6407" . "3"^^ . "26" . . . "[3D513CA62639]" . "Ordered Functionalized Silica Materials with High Proton Conductivity" . "1"^^ . "silica; high proton conductivity; Si-MCM-41"@en . "RIV/61388955:_____/07:00093586" . "Byla vyvinuta jednoduch\u00E1 a rychl\u00E1 metoda pro p\u0159\u00EDpravu silik\u00E1tov\u00FDch MCM-41 molekulov\u00FDch s\u00EDt funkcionalizovan\u00FDch sulfonov\u00FDmi skupinami zalo\u017Een\u00E1 na kopolymerizace a mikrovlnn\u00E9 iradiaci pro efektivn\u00ED odstran\u011Bn\u00ED templ\u00E1tu se sou\u010Dasnou oxidac\u00ED thiolov\u00FDch skupin na sulfonov\u00E9. Z\u00EDskan\u00E9 hybridn\u00ED materi\u00E1ly vykazuj\u00ED velmi vysokou protonovou vodivost 0.2 S/cm p\u0159i 100 %-n\u00ED relativn\u00ED vlhkosti. Protonov\u00E1 vodivost t\u011Bchto materi\u00E1l\u016F spojit\u011B vyr\u016Fst\u00E1 s teplotou. Je dosa\u017Eeno tak vysok\u00E9ho stupn\u011B zapln\u011Bn\u00ED p\u00F3r\u016F molekulov\u00E9ho s\u00EDta propylov\u00FDmi \u0159et\u011Bzci nesouc\u00EDmi sulfonov\u00E9 skupiny, \u017Ee na 1 nm2 vnit\u0159n\u00EDho povrchu p\u0159ipad\u00E1 v\u00EDce ne\u017E jedna SO3H skupina."@cs . "439973" . . "Ordered Functionalized Silica Materials with High Proton Conductivity" . "Chemistry of Materials" . . . . "P\u0159\u00EDprava uspo\u0159\u00E1dan\u00FDch funkcionalizovan\u00FDch silikov\u00FDch materi\u00E1l\u016F s vysokou protonovou vodivost\u00ED pomoc\u00ED mikrovlnn\u00E9 techniky"@cs . . "P(1M0577), R, Z(AV0Z40400503)" . "Ordered Functionalized Silica Materials with High Proton Conductivity"@en .