"1"^^ . "Studium elektrochemick\u00E9 inzerce Li kombinovan\u00E9 se strukturn\u00ED a texturn\u00ED anal\u00FDzou umo\u017Enilo identifikovat a kvantifikovat jednotliv\u00E9 krystalick\u00E9 a amorfn\u00ED f\u00E1ze v mesopor\u00E9zn\u00EDch filmech TiO2 p\u0159ipraven\u00FDch metodou EISA. Bylo zji\u0161t\u011Bno, \u017Ee vlastnosti amfifiln\u00EDch blokov\u00FDch kopolymer\u016F pou\u017Eit\u00FDch jako templ\u00E1ty, speci\u00E1ln\u011B nov\u00E9ho polymeru KLE a komer\u010Dn\u00EDho Pluroniku P123, rozhoduj\u00EDc\u00EDm zp\u016Fsobem ovliv\u0148uj\u00ED fyzik\u00E1ln\u011B-chemick\u00E9 vlastnosti v\u00FDsledn\u00FDch film\u016F. Filmy templ\u00E1tovan\u00E9 KLE maj\u00ED trojrozm\u011Brnou kubickou mesopor\u00E9zn\u00ED strukturu a jsou prakticky amorfn\u00ED, pokud je teplota kalcinace ni\u017E\u0161\u00ED ne\u017E 450oC. Kalcinace p\u0159i 550 700oC vede k pln\u011B krystalick\u00E9mu materi\u00E1lu slo\u017Een\u00E9mu z jedin\u00E9 krystalick\u00E9 f\u00E1ze anatasu p\u0159i zachov\u00E1n\u00ED intaktn\u00ED mesopor\u00E9zn\u00ED architektury. Elektrochemicky stanoven\u00FD pod\u00EDl krystalick\u00E9ho ananasu vzr\u016Fst\u00E1 z 85 na 100 % pro filmy kalcinovan\u00E9 p\u0159i 550 a 700oC."@cs . "17" . . "Vysoce organizovan\u00E9 mesopor\u00E9zn\u00ED filmy TiO2 s \u0159\u00EDzenou krystalinitou \u2013 studie inzerce Li"@cs . . "P(1M0577), R, Z(AV0Z40400503)" . . "10"^^ . . . "[4C9F9CCB794A]" . . . . "A study of electrochemical Li insertion combined with structural and textural analysis enabled the identification and quantification of individual crystalline and amorphous phases in mesoporous TiO2 films prepared by the evaporation-induced self-assembly procedure. It was found that the properties of the amphiphilic block copolymers used as templates, namely those of a novel poly(ethylene-co-butylene)-b-poly(ethylene oxide) polymer (KLE) and commercial Pluronic P123 (HO(CH2CH2O)(20)(CH2CH(CH3)O)(70)(CH2CH2O)(20)H), decisively influence the physicochemical properties of the resulting films. The KLE-templated films possess a 3D cubic mesoporous structure and are practically amorphous when calcined at temperatures below 450 degrees C. but treatment at 550-700 degrees C provides a pure-phase (anatase), fully crystalline material with intact mesoporous architecture."@en . "Advanced Functional Materials" . "Highly organized mesoporous TiO2 films with controlled crystallinity: A Li-insertion study"@en . . "424129" . "Rathousk\u00FD, Ji\u0159\u00ED" . "Wark, M." . "DE - Spolkov\u00E1 republika N\u011Bmecko" . "RIV/61388955:_____/07:00088012!RIV08-MSM-61388955" . . "Vysoce organizovan\u00E9 mesopor\u00E9zn\u00ED filmy TiO2 s \u0159\u00EDzenou krystalinitou \u2013 studie inzerce Li"@cs . "Brezesinski, T." . "Highly organized mesoporous TiO2 films with controlled crystallinity: A Li-insertion study"@en . . "Highly organized mesoporous TiO2 films with controlled crystallinity: A Li-insertion study" . "Smarsly, B. M." . . "123;132" . "1" . "titania; thin films; lithium insertion; anatase electrodes"@en . . . "RIV/61388955:_____/07:00088012" . "5"^^ . . . . "Highly organized mesoporous TiO2 films with controlled crystallinity: A Li-insertion study" . "Fattakhova Rohlfing, D." . . . "1616-301X" . "A study of electrochemical Li insertion combined with structural and textural analysis enabled the identification and quantification of individual crystalline and amorphous phases in mesoporous TiO2 films prepared by the evaporation-induced self-assembly procedure. It was found that the properties of the amphiphilic block copolymers used as templates, namely those of a novel poly(ethylene-co-butylene)-b-poly(ethylene oxide) polymer (KLE) and commercial Pluronic P123 (HO(CH2CH2O)(20)(CH2CH(CH3)O)(70)(CH2CH2O)(20)H), decisively influence the physicochemical properties of the resulting films. The KLE-templated films possess a 3D cubic mesoporous structure and are practically amorphous when calcined at temperatures below 450 degrees C. but treatment at 550-700 degrees C provides a pure-phase (anatase), fully crystalline material with intact mesoporous architecture." .