. . "1" . "Funkcionalizovan\u00E9 mesopor\u00E9zn\u00ED filmy SiO2 jako elektrodov\u00E9 vrstvy pro elektrochemick\u00E9 aplikace"@cs . "0925-4005" . "78;81" . "RIV/61388955:_____/07:00087862!RIV08-MSM-61388955" . . . "Sensors and Actuators B - Chemical" . . . . "4"^^ . "P(1M0577), V, Z(AV0Z40400503)" . "Uspo\u0159\u00E1dan\u00E9 funkcionalizovan\u00E9 mesopor\u00E9zn\u00ED filmy SiO2 byly pou\u017Eity jako vrstvy na elektrod\u00E1ch pro r\u016Fzn\u00E9 elektrochemick\u00E9 aplikace v z\u00E1vislosti na povaze zaveden\u00FDch funk\u010Dn\u00EDch skupin. Filmy funkcionalizovan\u00E9 kationick\u00FDmi tetraalkylamoniov\u00FDmi skupinami slou\u017E\u00ED jako matrice pro elektrostatickou imobilizaci polyoxometal\u00E1tov\u00FDch a hexacyanofer\u00E1tov\u00FDch aniont\u016F. Elektroaktivn\u00ED koncentrace redox speci\u00ED ve vrstv\u00E1ch dosahuje 90 a 260 micromol/cm3 pro iontov\u011B v\u00E1zan\u00E9 polyoxometal\u00E1ty a hexacyanofer\u00E1ty, a je n\u011Bkolikr\u00E1t vy\u0161\u0161\u00ED ve srovn\u00E1n\u00ED s monovrstvou na elektrod\u011B. Filmy funkcionalizovan\u00E9 protonovateln\u00FDmi aminoskupinami u\u010Dinkuj\u00ED jako efektivn\u00ED permselektivn\u00ED membr\u00E1ny \u0159\u00EDzen\u00E9 zm\u011Bnou pH. V z\u00E1vislosti na pH otev\u00EDraj\u00ED nebo zesiluj\u00ED tok hexacyanofer\u00E1tov\u00FDch aniont\u016F, zat\u00EDmco tok hexaaminorutheniov\u00FDch kationt\u016F k povrchu elektrody je blokov\u00E1n."@cs . . "mesoporous silica films; functionalization; modified electrodes"@en . . "RIV/61388955:_____/07:00087862" . . "3"^^ . "Funkcionalizovan\u00E9 mesopor\u00E9zn\u00ED filmy SiO2 jako elektrodov\u00E9 vrstvy pro elektrochemick\u00E9 aplikace"@cs . "Electrode layers for electrochemical applications based on functionalized mesoporous silica films"@en . "Fattakhova Rohlfing, D." . . . "Functionalized ordered mesoporous films of SiO2 have been used as electrode coatings for various electrochemical applications depending on the nature of introduced functional groups. The films functionalized with tetraalkylammonium cationic groups serve as a matrix for ionic immobilization of polyoxometalate- and hexacyanoferrate anions. The electroactive concentration of redox species within the layers achieves 90 and 260 micromol/cm3 for ionically bonded polyoxometalate and hexacyanoferrate, respectively, being several times higher comparing to a monolayer on an electrode. The films functionalized with protonable amino groups act as effective permselective membranes switchable by the change in pH. Depending on pH, they actuated or amplified the flux of hexacyanoferrate anions, while the flux of hexaaminoruthenium cations to the electrode surface was blocked."@en . "126" . . . "[EEB53D5F8027]" . "1"^^ . "Functionalized ordered mesoporous films of SiO2 have been used as electrode coatings for various electrochemical applications depending on the nature of introduced functional groups. The films functionalized with tetraalkylammonium cationic groups serve as a matrix for ionic immobilization of polyoxometalate- and hexacyanoferrate anions. The electroactive concentration of redox species within the layers achieves 90 and 260 micromol/cm3 for ionically bonded polyoxometalate and hexacyanoferrate, respectively, being several times higher comparing to a monolayer on an electrode. The films functionalized with protonable amino groups act as effective permselective membranes switchable by the change in pH. Depending on pH, they actuated or amplified the flux of hexacyanoferrate anions, while the flux of hexaaminoruthenium cations to the electrode surface was blocked." . . "CH - \u0160v\u00FDcarsk\u00E1 konfederace" . "Rathousk\u00FD, Ji\u0159\u00ED" . . "Electrode layers for electrochemical applications based on functionalized mesoporous silica films"@en . "Electrode layers for electrochemical applications based on functionalized mesoporous silica films" . . "419720" . "Wark, M." . "Electrode layers for electrochemical applications based on functionalized mesoporous silica films" . .