. "Mono and dinuclear rhodium, iridium and ruthenium complexes containing chelating 2,2\u00B4-bipyrimidine ligands: Synthesis, molecular structure, electrochemistry and catalytic properties" . "3664;3675" . "Mono and dinuclear rhodium, iridium and ruthenium complexes containing chelating 2,2\u00B4-bipyrimidine ligands: Synthesis, molecular structure, electrochemistry and catalytic properties"@en . . "Therrien, B." . . "arene ligands; electrochemistry; dinuclear complexes; transfer hydrogenation"@en . . "Ludv\u00EDk, Ji\u0159\u00ED" . "P(LC06070), Z(AV0Z40400503), Z(MSM0021620857)" . "CH - \u0160v\u00FDcarsk\u00E1 konfederace" . "The mononuclear cations [(eta5-C5Me5)RhCl(bpym)]+ (1), [(eta5-C5Me5)IrCl(bpym)]+ (2), [(eta6-p-PriC6H4Me)RuCl(bpym)]+ (3) and [(eta6-C6Me6)RuCl(bpym)]+ (4) as well as the dinuclear dications [{(eta5-C5Me5)RhCl}2(bpym)]2+ (5), [{(eta5-C5Me5)IrCl}2(bpym)]2+ (6), [{(eta6-p-PriC6H4Me)RuCl}2(bpym)]2+ (7) and [{(eta6-C6Me6)RuCl}2(bpym)]2+ (8) have been synthesised from 2,2\u00B4-bipyrimidine (bpym) and the corresponding chloro complexes [(eta5-C5Me5)RhCl2]2, [(eta5-C5Me5)IrCl2]2, [(eta6-PriC6H4Me)RuCl2]2 and [(eta6-C6Me6)RuCl2]2, respectively. The X-ray crystal structure analyses of [3][PF6], [5][PF6]2, [6][CF3SO3]2 and [7][PF6]2 reveal a typical piano-stool geometry around the metal centres; in the dinuclear complexes the chloro ligands attached to the two metal centres are found to be, with respect to each other, cis oriented for 5 and 6 but trans for 7. The electrochemical behaviour of 1\u20138 has been studied by voltammetric methods."@en . . "435017" . "[A6642916E58B]" . "RIV/61388955:_____/07:00085409!RIV08-MSM-61388955" . "The mononuclear cations [(eta5-C5Me5)RhCl(bpym)]+ (1), [(eta5-C5Me5)IrCl(bpym)]+ (2), [(eta6-p-PriC6H4Me)RuCl(bpym)]+ (3) and [(eta6-C6Me6)RuCl(bpym)]+ (4) as well as the dinuclear dications [{(eta5-C5Me5)RhCl}2(bpym)]2+ (5), [{(eta5-C5Me5)IrCl}2(bpym)]2+ (6), [{(eta6-p-PriC6H4Me)RuCl}2(bpym)]2+ (7) and [{(eta6-C6Me6)RuCl}2(bpym)]2+ (8) have been synthesised from 2,2\u00B4-bipyrimidine (bpym) and the corresponding chloro complexes [(eta5-C5Me5)RhCl2]2, [(eta5-C5Me5)IrCl2]2, [(eta6-PriC6H4Me)RuCl2]2 and [(eta6-C6Me6)RuCl2]2, respectively. The X-ray crystal structure analyses of [3][PF6], [5][PF6]2, [6][CF3SO3]2 and [7][PF6]2 reveal a typical piano-stool geometry around the metal centres; in the dinuclear complexes the chloro ligands attached to the two metal centres are found to be, with respect to each other, cis oriented for 5 and 6 but trans for 7. The electrochemical behaviour of 1\u20138 has been studied by voltammetric methods." . "12"^^ . . . "S\u00FCss-Fink, G." . "Journal of Organometallic Chemistry" . "\u0160t\u011Bpni\u010Dka, P." . "1"^^ . . . . "Jedno- a dvojjadern\u00E9 komplexy iridia, rhodia a ruthenia, kter\u00E9 obsahuj\u00ED chel\u00E1tuj\u00EDc\u00ED karboxyl\u00E1to-pyrazinov\u00E9 ligandy: Synt\u00E9za, molekul\u00E1rn\u00ED struktura a elektrochemie"@cs . . . "Canivet, J." . . . "Govindaswamy, P." . . . "6"^^ . . "17" . . "0022-328X" . "Mono and dinuclear rhodium, iridium and ruthenium complexes containing chelating 2,2\u00B4-bipyrimidine ligands: Synthesis, molecular structure, electrochemistry and catalytic properties"@en . "Jedno- a dvojjadern\u00E9 Ir, Rh a Ru komplexy obsahuj\u00EDc\u00ED sou\u010Dasn\u011B %22m\u011Bkk\u00E9%22 chel\u00E1tuj\u00EDc\u00ED organick\u00E9 a %22tvrd\u00E9%22 hydrofiln\u00ED ligandy p\u0159edstavuj\u00ED stavebn\u00ED jednotky pro supramolekul\u00E1rn\u00ED materi\u00E1ly a sou\u010Dasn\u011B jsou slibn\u00FDmi hydrogena\u010Dn\u00EDmi katalyz\u00E1tory. Elektrochemick\u00E9 studium oxidace seri\u00ED t\u011Bchto slou\u010Denin, kter\u00E9 obsahuj\u00ED karboxyl\u00E1to-pyrazinov\u00E9 ligandy umo\u017Enilo charakterizovat jejich redox vlastnosti a intramolekul\u00E1rn\u00ED elektronick\u00E9 interakce a korelovat je s katalytickou aktivitou. Z hlediska supramolekul\u00E1rn\u00ED chemie bylo zji\u0161t\u011Bno, \u017Ee vhodn\u00E1 substituce umo\u017En\u00ED oxidativn\u00ED dimerizaci t\u011Bchto l\u00E1tek."@cs . "RIV/61388955:_____/07:00085409" . . "Mono and dinuclear rhodium, iridium and ruthenium complexes containing chelating 2,2\u00B4-bipyrimidine ligands: Synthesis, molecular structure, electrochemistry and catalytic properties" . "692" . "Jedno- a dvojjadern\u00E9 komplexy iridia, rhodia a ruthenia, kter\u00E9 obsahuj\u00ED chel\u00E1tuj\u00EDc\u00ED karboxyl\u00E1to-pyrazinov\u00E9 ligandy: Synt\u00E9za, molekul\u00E1rn\u00ED struktura a elektrochemie"@cs .