. "Zones, S. I." . "Highly selective synthesis of acetylferrocene by acylation of ferrocene over zeolites"@en . . "424133" . . . . "Selektivn\u00ED synt\u00E9za acetylferrocenu acylac\u00ED ferrocenu na zeolitech"@cs . "Highly selective synthesis of acetylferrocene by acylation of ferrocene over zeolites" . . . . "0926-860X" . "NL - Nizozemsko" . . "RIV/61388955:_____/07:00085031" . "Zeolites with different structure and concentration of acid sites were investigated in a liquid phase acylation of ferrocene with acetic anhydride. It was found that the conversion of ferrocene increased in the order: medium pore zeolites < 1D large pore zeolites < 3D large pore zeolites. Zeolite SSZ-33 with interconnecting 10 and 12-membered rings exhibited a slightly lower conversion compared with mordenite. The increase in the conversion of ferrocene was observed with decreasing Si/Al ratio for the given zeolite structure. Both Broensted and Lewis acid sites contribute to the catalytic activity of zeolites in ferrocene acylation. Mono-acylated ferrocene (acetylferrocene) was synthesized by this reaction with almost 100% selectivity." . . . "Highly selective synthesis of acetylferrocene by acylation of ferrocene over zeolites"@en . "Highly selective synthesis of acetylferrocene by acylation of ferrocene over zeolites" . "Applied Catalysis A - General" . "255;260" . "Bejblov\u00E1, Martina" . "6"^^ . "2"^^ . . . "Zeolites with different structure and concentration of acid sites were investigated in a liquid phase acylation of ferrocene with acetic anhydride. It was found that the conversion of ferrocene increased in the order: medium pore zeolites < 1D large pore zeolites < 3D large pore zeolites. Zeolite SSZ-33 with interconnecting 10 and 12-membered rings exhibited a slightly lower conversion compared with mordenite. The increase in the conversion of ferrocene was observed with decreasing Si/Al ratio for the given zeolite structure. Both Broensted and Lewis acid sites contribute to the catalytic activity of zeolites in ferrocene acylation. Mono-acylated ferrocene (acetylferrocene) was synthesized by this reaction with almost 100% selectivity."@en . . "Selektivn\u00ED synt\u00E9za acetylferrocenu acylac\u00ED ferrocenu na zeolitech"@cs . . . "[F589492BF321]" . "acetylferrocene; acylation; zeolites; structural types"@en . "3"^^ . . . . "RIV/61388955:_____/07:00085031!RIV08-AV0-61388955" . "Pro acylaci ferrocenu v kapaln\u00E9 f\u00E1zi anhydritem kyseliny octov\u00E9 byla testov\u00E1na cel\u00E1 \u0159ada r\u016Fzn\u00FDch zeolitick\u00FDch katalyz\u00E1tor\u016F li\u0161\u00EDc\u00EDch se svou strukturou a koncentrac\u00ED kysel\u00FDch aktivn\u00EDch center. Bylo zji\u0161t\u011Bno, \u017Ee konverze ferrocenu roste v po\u0159ad\u00ED: st\u0159edn\u011B por\u00E9zn\u00ED zeolity < 1D \u0161irokopor\u00E9zn\u00ED zeolity < 3D \u0161irokopor\u00E9zn\u00ED zeolity. V\u00FDsledn\u00E1 konverze ferrocene byla d\u00E1le ovlivn\u011Bna pom\u011Brem Si/Al (s klesaj\u00EDc\u00EDm pom\u011Brem Si/Al rostla konverze ferrocenu). Uk\u00E1zalo se, \u017Ee jak Broenstedova tak Lewisova kysel\u00E1 centra p\u0159isp\u00EDvaj\u00ED ke katalytick\u00E9 aktivit\u011B zeolit\u016F p\u0159i studovan\u00E9 aclyla\u010Dn\u00ED reakci. Selektivita mono-acylovan\u00E9ho ferrocenu byla t\u00E9m\u011B\u0159 100%."@cs . "P(GA104/07/0383), P(IAB4040201), Z(AV0Z40400503)" . . "\u010Cejka, Ji\u0159\u00ED" . "2" . "327" .