"0013-4686" . "10"^^ . "3"^^ . "The effect of the inner particle structure on Li insertion activity and electronic structure of the nano-crystalline Li-Ti-O spinels was studied on materials prepared by solid state and solvothermal synthesis. The high temperature prepared materials of composition corresponding to Li4Ti5O12 feature particles with characteristic size of ca. 200 nm with randomly distributed defects. The products of solvothermal synthesis with composition Li1.1Ti1.9O4+delta, feature cubic particles of characteristic dimension of ca. 50 nm; the characteristic particle size differs from that of the coherent domain determined by X-ray diffraction. The reduction of the solvothermal and high temperature synthesized nano-crystalline spinels in Li containing solutions leads according to Li-6 MAS NMR spectra to Li insertion into tetrahedral 8b and octahedral 16c position, respectively."@en . "solvothermal synthesis; Li-insertion; nano-crystalline spinel; UV-vis-NIR spectra"@en . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . "The effect of the inner particle structure on the electronic structure of the nano-crystalline Li-Ti-O spinels" . . "The effect of the inner particle structure on the electronic structure of the nano-crystalline Li-Ti-O spinels"@en . . "1847;1856" . . . "The effect of the inner particle structure on Li insertion activity and electronic structure of the nano-crystalline Li-Ti-O spinels was studied on materials prepared by solid state and solvothermal synthesis. The high temperature prepared materials of composition corresponding to Li4Ti5O12 feature particles with characteristic size of ca. 200 nm with randomly distributed defects. The products of solvothermal synthesis with composition Li1.1Ti1.9O4+delta, feature cubic particles of characteristic dimension of ca. 50 nm; the characteristic particle size differs from that of the coherent domain determined by X-ray diffraction. The reduction of the solvothermal and high temperature synthesized nano-crystalline spinels in Li containing solutions leads according to Li-6 MAS NMR spectra to Li insertion into tetrahedral 8b and octahedral 16c position, respectively." . "Kostl\u00E1nov\u00E1, Tereza" . "3"^^ . . . . . . "Electrochimica acta" . "The effect of the inner particle structure on the electronic structure of the nano-crystalline Li-Ti-O spinels" . . . . . "RIV/61388955:_____/07:00082475" . . . "RIV/61388955:_____/07:00082475!RIV08-AV0-61388955" . . "The effect of the inner particle structure on the electronic structure of the nano-crystalline Li-Ti-O spinels"@en . . . "Byl studov\u00E1n vliv vnit\u0159n\u00ED struktury \u010D\u00E1stic na aktivitu inzerce Li a elektronovou strukturu nanokrystalick\u00FDch Li-Ti-O spinel\u016F p\u0159ipraven\u00FDch synt\u00E9zou v pevn\u00ED f\u00E1zi a solvoterm\u00E1ln\u00ED synt\u00E9zou. Vysokoteplotn\u011B p\u0159ipraven\u00E9 materi\u00E1ly s odpov\u00EDdaj\u00EDc\u00EDm slo\u017Een\u00EDm a stechiometrii Li4Ti5O12 maj\u00ED charakteristickou velikost \u010D\u00E1stic cca 200 nm s n\u00E1hodn\u011B distribuovan\u00FDmi defekty. Produkty solvoterm\u00E1ln\u00ED synt\u00E9zy se slo\u017Een\u00EDm typu Li1.1Ti1.9O4+.delta. vykazuj\u00ED \u010D\u00E1stice s charakteristickou velikost\u00ED cca 50 nm; charakteristick\u00E1 velikost \u010D\u00E1stic se li\u0161\u00ED od velikosti koherentn\u00ED dom\u00E9ny ur\u010Den\u00E9 na z\u00E1klad\u011B rentgenov\u00E9 difrakce. Redukce solvoterm\u00E1ln\u011B (vysokoteplotn\u011B) p\u0159ipraven\u00E9ho nanokrystalick\u00E9ho spinelu z roztoku obsahuj\u00EDc\u00ED Li vede, na z\u00E1klad\u011B nam\u011B\u0159en\u00FDch 6Li MAS NMR spekter, k inzerci Li do tetraedrick\u00FDch (oktaedrick\u00FDch) pozic typu 8b (16c). Ve spektrech \u010D\u00E1ste\u010Dn\u011B redukovan\u00E9ho vysokoteplotn\u00EDho spinelu byl pozorov\u00E1n dodate\u010Dn\u00FD \u0161irok\u00FD NMR sign\u00E1l odpov\u00EDdaj\u00EDc\u00ED Knightovu posunu."@cs . . "Vliv vnit\u0159n\u00ED struktury \u010D\u00E1stic na elektronovou strukturu nanokrystalick\u00FDch Li-Ti-O spinel\u016F"@cs . . "5" . "Krtil, Petr" . "419149" . "P(GA203/03/0823), Z(AV0Z40400503)" . "Vliv vnit\u0159n\u00ED struktury \u010D\u00E1stic na elektronovou strukturu nanokrystalick\u00FDch Li-Ti-O spinel\u016F"@cs . "D\u011Bde\u010Dek, Ji\u0159\u00ED" . "[D55F0272C057]" . "52" .