. . . . "487463" . "23" . "RIV/61388955:_____/06:00085399" . "Review shrnuj\u00EDc\u00ED rozs\u00E1hl\u00E9 elektrochemick\u00E9 studium n\u011Bkolika seri\u00ED aminokarbenov\u00FDch komplex\u016F Cr, W a Fe s r\u016Fzn\u00FDmi (chel\u00E1tov\u00FDmi a nechel\u00E1tov\u00FDmi) ligandy a s r\u016Fznou substituc\u00ED na karbenov\u00E9m fenylu. Krom\u011B lokalizace oxida\u010Dn\u00EDch a reduk\u010Dn\u00EDch center a jejich vz\u00E1jemn\u00E9 interakce byl diskutov\u00E1n vztah elektrochemick\u00FDch dat a energetick\u00FDch rozd\u00EDl\u016F hladin HOMO a LUMO a vliv substituce na redox vlastnosti, p\u0159i\u010Dem\u017E byly sledov\u00E1ny t\u00E9\u017E zm\u011Bny v elektronov\u00E9 delokalizaci zp\u016Fsoben\u00E9 sterick\u00FDmi vlivy."@cs . . "9"^^ . "Roh\u00E1\u010Dov\u00E1, J." . "2" . . "M(0) \u2013 aminokarbenov\u00E9 komplexy chromu, wolframu a \u017Eeleza: Redoxn\u00ED chov\u00E1n\u00ED ovliv\u0148ovan\u00E9 (\u201Elad\u011Bn\u00E9\u201C) zm\u011Bnami kovu a/nebo ligandu"@cs . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . "M(0) - Aminocarbene complexes (M = Cr, W, Fe): Redox Behavior Tuned by Metal and/or ligand modification"@en . "M(0) - Aminocarbene complexes (M = Cr, W, Fe): Redox Behavior Tuned by Metal and/or ligand modification" . "Dvo\u0159\u00E1k, D." . . "Series of chromium, tungsten and iron aminocarbene complexes were prepared and electrochemically investigated. The influence of the type of coordination, of the substituent on the ligand phenyl ring and of the central metal atom on oxidation and reduction potentials was followed electrochemically using the Linear Free Energy Relationship (LFER) approach. The difference between the oxidation and reduction potentials reflects the energy of the HOMO-LUMO gap. The reduction of carbene derivatives strongly depends only on the nature of ligands and their substitution, but not on the nature of the central metal. On the other hand, the oxidation is practically independent of the ligand substitution, being influenced by both the nature of the central metal atom and the number of carbonyl groups (i.e. strong pi-acceptors) present." . . "M(0) - Aminocarbene complexes (M = Cr, W, Fe): Redox Behavior Tuned by Metal and/or ligand modification"@en . "carbene complexes; electrochemistry"@en . "P(GA203/04/0487), Z(AV0Z40400503)" . . . "4"^^ . "[B941EF9689D9]" . "M(0) \u2013 aminokarbenov\u00E9 komplexy chromu, wolframu a \u017Eeleza: Redoxn\u00ED chov\u00E1n\u00ED ovliv\u0148ovan\u00E9 (\u201Elad\u011Bn\u00E9\u201C) zm\u011Bnami kovu a/nebo ligandu"@cs . . . "Ludv\u00EDk, Ji\u0159\u00ED" . "RIV/61388955:_____/06:00085399!RIV08-AV0-61388955" . "M(0) - Aminocarbene complexes (M = Cr, W, Fe): Redox Behavior Tuned by Metal and/or ligand modification" . "1"^^ . "ECS Transactions" . "1938-5862" . "87;95" . . . "Hoskovcov\u00E1, I." . . "Series of chromium, tungsten and iron aminocarbene complexes were prepared and electrochemically investigated. The influence of the type of coordination, of the substituent on the ligand phenyl ring and of the central metal atom on oxidation and reduction potentials was followed electrochemically using the Linear Free Energy Relationship (LFER) approach. The difference between the oxidation and reduction potentials reflects the energy of the HOMO-LUMO gap. The reduction of carbene derivatives strongly depends only on the nature of ligands and their substitution, but not on the nature of the central metal. On the other hand, the oxidation is practically independent of the ligand substitution, being influenced by both the nature of the central metal atom and the number of carbonyl groups (i.e. strong pi-acceptors) present."@en . .