"-" . "13" . "4"^^ . . . . . "DE - Spolkov\u00E1 republika N\u011Bmecko" . "New organometallic nickel complexes of the type [( alpha -diimine)Ni(Mes)Br] and [ alpha -diimine)Ni(Mes)2] (Mes = mesityl = 2,4,6-trimethylphenyl) were prepared and characterized spectroscopically in detail. A combination of spectroscopic techniques (XRD, EXAFS, absorption, resonance Raman) and quantum chemical (DFT) calculations reveal the interplay of the diimine ligands and the co-ligands mesityl or bromine with the nickel centre. The low-lying electronic transitions are assigned to mixed MLCT/L'LCT or MLCT/XLCT due to low-lying accepting .p\u00ED.*-orbitals centered on the diimine ligands and mixed metal/co-ligand MOs as donor levels." . . "13"^^ . "1"^^ . "577870" . . "[BF10B75AAACB]" . . . "New organometallic nickel complexes of the type [( alpha -diimine)Ni(Mes)Br] and [ alpha -diimine)Ni(Mes)2] (Mes = mesityl = 2,4,6-trimethylphenyl) were prepared and characterized spectroscopically in detail. A combination of spectroscopic techniques (XRD, EXAFS, absorption, resonance Raman) and quantum chemical (DFT) calculations reveal the interplay of the diimine ligands and the co-ligands mesityl or bromine with the nickel centre. The low-lying electronic transitions are assigned to mixed MLCT/L'LCT or MLCT/XLCT due to low-lying accepting .p\u00ED.*-orbitals centered on the diimine ligands and mixed metal/co-ligand MOs as donor levels."@en . "On the Electronic Structure of Mesitylnickel Complexes of .alpha.-Diimines-Combining Structural Data, Spectroscopy and Calculations"@en . "Feth, M. P." . "European Journal of Inorganic Chemistry" . . "2784;2796" . . "Elektronov\u00E1 struktura mesitylenov\u00FDch komplex\u016F niklu s alfa-diiminy z\u00EDskan\u00E1 kombinac\u00ED strukturn\u00EDch dat, spektroskopi\u00ED a v\u00FDpo\u010Dt\u016F"@cs . "1434-1948" . . . . "On the Electronic Structure of Mesitylnickel Complexes of .alpha.-Diimines-Combining Structural Data, Spectroscopy and Calculations" . "On the Electronic Structure of Mesitylnickel Complexes of .alpha.-Diimines-Combining Structural Data, Spectroscopy and Calculations"@en . "On the Electronic Structure of Mesitylnickel Complexes of .alpha.-Diimines-Combining Structural Data, Spectroscopy and Calculations" . "P(OC D14.20), Z(AV0Z4040901)" . "Elektronov\u00E1 struktura mesitylenov\u00FDch komplex\u016F niklu s alfa-diiminy z\u00EDskan\u00E1 kombinac\u00ED strukturn\u00EDch dat, spektroskopi\u00ED a v\u00FDpo\u010Dt\u016F"@cs . "Mono- a dinukle\u00E1rn\u00ED organometalick\u00E9 komplexy niklu typu [(alpha-diimine)Ni(Mes)Brn] (n = 1 or 2) and [(alpha-diimine)Ni(Mes)2] (Mes = mesityl = 2,4,6-trimethylphenyl) byly p\u0159ipraveny a detailn\u011B charakterizov\u00E1ny. Krystalov\u00E1 struktura [(tmphen)Ni(Mes)2] a EXAFS studie vybran\u00FDch vzork\u016F popisuj\u00ED strukturn\u00ED charakteristiky t\u011Bchto komplex\u016F. Elektronov\u00E1 struktura t\u011Bchto komplex\u016F byla zkoum\u00E1na kombinac\u00ED spektroskopick\u00FDch technik (absorp\u010Dn\u00ED, resonan\u010Dn\u00ED Ramanovou spektroskopie) a kvantov\u011B chemick\u00FDmi (DFT) v\u00FDpo\u010Dty."@cs . "RIV/61388955:_____/04:00101112!RIV/2005/AV0/A54005/N" . "Bertagnolli, H." . . . "density functional calculations; electronic structure; Raman spectroscopy"@en . "Klein, A." . . . "Z\u00E1li\u0161, Stanislav" . "RIV/61388955:_____/04:00101112" .