. . "Quasi-elastic laser light scattering and impedance measurements at water/1,2-dichloroethane interface are used to evaluate the interfacial tension and the differential capacity, respectively, as a function of the interfacial potential difference. Over the range of the potential differences around the zero-charge potential difference, the surface charge density obtained by integration of the capacity agrees well with that obtained by derivation of the interfacial tension. However, the ratio of these two charges starts to deviate significantly from unity close to the potential window limits, where the faradaic current associated with the transfer of the supporting electrolyte ions becomes more pronounced, and where the capacity shows a remarkable enhancement. In the range of the potential differences, where the capacity data can be reliably obtained, a weak effect of the nature of the organic electrolyte on both the interfacial tension and the differential capacity is observed."@en . "Samec, Zden\u011Bk" . "0022-0728" . "Omezen\u00E1 shoda mezi \u00FAdaji o povrchov\u00E1 nap\u011Bt\u00EDm a diferenci\u00E1ln\u00ED kapacit\u011B polarizovan\u00E9ho rozhran\u00ED voda/1,2-dichlorethan"@cs . "8"^^ . "Troj\u00E1nek, Anton\u00EDn" . . . . . "Limited Agreement between the Interfacial Tension and Differential Capacity Data for the Polarised Water|1,2-dichloroethane Interface" . . "RIV/61388955:_____/04:00101041!RIV/2005/AV0/A54005/N" . "RIV/61388955:_____/04:00101041" . "Lhotsk\u00FD, Alexandr" . . "P(ME 502), Z(AV0Z4040901)" . "Mare\u010Dek, Vladim\u00EDr" . . "[FF73C529C9D7]" . . "Journal of Electroanalytical Chemistry" . . "CH - \u0160v\u00FDcarsk\u00E1 konfederace" . "Quasi-elastic laser light scattering and impedance measurements at water/1,2-dichloroethane interface are used to evaluate the interfacial tension and the differential capacity, respectively, as a function of the interfacial potential difference. Over the range of the potential differences around the zero-charge potential difference, the surface charge density obtained by integration of the capacity agrees well with that obtained by derivation of the interfacial tension. However, the ratio of these two charges starts to deviate significantly from unity close to the potential window limits, where the faradaic current associated with the transfer of the supporting electrolyte ions becomes more pronounced, and where the capacity shows a remarkable enhancement. In the range of the potential differences, where the capacity data can be reliably obtained, a weak effect of the nature of the organic electrolyte on both the interfacial tension and the differential capacity is observed." . . "Kvazieleastick\u00FD rozptyl sv\u011Btla a impedan\u010Dn\u00ED spektroskopie byly pou\u017Eity k vyhodnocen\u00ED povrchov\u00E9ho nap\u011Bt\u00ED a diferenci\u00E1ln\u00ED kapacity rozhran\u00ED voda/1,2-dichlorethan jako funkce mezif\u00E1zov\u00E9ho potenci\u00E1lov\u00E9ho rozd\u00EDlu. V okol\u00ED potenci\u00E1lov\u00E9ho rozd\u00EDlu nulov\u00E9ho n\u00E1boje byla zji\u0161t\u011Bna dobr\u00E1 shoda mezi n\u00E1boji ur\u010Den\u00FDmi integrac\u00ED kapacitn\u00EDch k\u0159ivek a derivac\u00ED elektrokapil\u00E1rn\u00EDch k\u0159ivek. P\u0159i vy\u0161\u0161\u00EDch hodnot\u00E1ch potenci\u00E1lov\u00E9ho rozd\u00EDlu, zejm\u00E9na v oblasti n\u00E1r\u016Fstu faradaick\u00E9ho proudu p\u0159enosu iont\u016F z\u00E1kladn\u00EDch elektrolyt\u016F, v\u0161ak pom\u011Br t\u011Bchto n\u00E1boj\u016F v\u00FDznamn\u011B vy\u0161\u0161\u00ED ne\u017E jedna. Tyto v\u00FDsledky jsou v souladu s na\u0161\u00EDm p\u0159edchoz\u00EDm pozorov\u00E1n\u00EDm a z\u00E1v\u011Bry zpochyb\u0148uj\u00EDc\u00EDmi interpretaci diferenci\u00E1ln\u00ED kapacity na z\u00E1klad\u011B asociace iont\u016F, jejich specifick\u00E9 adsorpce p\u0159\u00EDpadn\u011B pronik\u00E1n\u00ED do opa\u010Dn\u00E9 f\u00E1ze."@cs . "1/2" . . . "Limited Agreement between the Interfacial Tension and Differential Capacity Data for the Polarised Water|1,2-dichloroethane Interface" . . "4"^^ . "Omezen\u00E1 shoda mezi \u00FAdaji o povrchov\u00E1 nap\u011Bt\u00EDm a diferenci\u00E1ln\u00ED kapacit\u011B polarizovan\u00E9ho rozhran\u00ED voda/1,2-dichlorethan"@cs . "Limited Agreement between the Interfacial Tension and Differential Capacity Data for the Polarised Water|1,2-dichloroethane Interface"@en . "565" . "571559" . "quasi-elastic laser light scattering; immiscible electrolyte solutions; differential capacity"@en . . "4"^^ . . "243;250" . . "Limited Agreement between the Interfacial Tension and Differential Capacity Data for the Polarised Water|1,2-dichloroethane Interface"@en . . .