"1"^^ . "RIV/61388955:_____/02:54020193" . "DE - Spolkov\u00E1 republika N\u011Bmecko" . "The new complexes (RN=CH-CH=NR)Co(NO)(CO), R = isopropyl (1), 2,6-diisopropylphenyl (2) and p-tolyl (3), were synthesized and spectroscopically characterized. Compounds I and 2 could be crystallized for X-ray structure analysis, CO/NO disorder was observed for 1. The results indicate a negligible amount of charge transfer from the Co(NO)(CO) moiety to the 1,4-diaza-butadiene acceptor ligands in the ground state, in agreement with DFT calculations on I and as similarly reported for related 1,4-diaza-1,3-butadiene complexes of Ni(CO)(2) and Fe(NO)(2)."@en . "Geometrical and ground state electronic structures of nitrosylcobalt complexes [(RNCHCHNR)Co(NO)(CO)] (R = isopropyl, 2,6-diisopropylphenyl or p-tolyl) from experiment and DFT-calculations."@en . "[F5E4AE2AD800]" . . . "647084" . . "N/A" . . "Zeitschrift f\u00FCr Anorganische und Allgemeine Chemie" . . "carbonyl complexes; cobalt compounds; DFT calculations"@en . . "628" . "RIV/61388955:_____/02:54020193!RIV/2003/AV0/A54003/N" . . "Kaim, W." . "0044-2313" . "2360;2364" . . . . . "Hubler, K." . . "Scheiring, T." . "Sieger, M." . "Geometrical and ground state electronic structures of nitrosylcobalt complexes [(RNCHCHNR)Co(NO)(CO)] (R = isopropyl, 2,6-diisopropylphenyl or p-tolyl) from experiment and DFT-calculations."@en . "6"^^ . "Geometrical and ground state electronic structures of nitrosylcobalt complexes [(RNCHCHNR)Co(NO)(CO)] (R = isopropyl, 2,6-diisopropylphenyl or p-tolyl) from experiment and DFT-calculations." . "5"^^ . . "0"^^ . . . "0"^^ . "P(OC D14.20), Z(AV0Z4040901)" . "The new complexes (RN=CH-CH=NR)Co(NO)(CO), R = isopropyl (1), 2,6-diisopropylphenyl (2) and p-tolyl (3), were synthesized and spectroscopically characterized. Compounds I and 2 could be crystallized for X-ray structure analysis, CO/NO disorder was observed for 1. The results indicate a negligible amount of charge transfer from the Co(NO)(CO) moiety to the 1,4-diaza-butadiene acceptor ligands in the ground state, in agreement with DFT calculations on I and as similarly reported for related 1,4-diaza-1,3-butadiene complexes of Ni(CO)(2) and Fe(NO)(2)." . . "Z\u00E1li\u0161, Stanislav" . "Geometrical and ground state electronic structures of nitrosylcobalt complexes [(RNCHCHNR)Co(NO)(CO)] (R = isopropyl, 2,6-diisopropylphenyl or p-tolyl) from experiment and DFT-calculations." . "Sixt, T." . .