. "R" . "9" . . "22340" . . "2"^^ . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . "Golemme, Giovanni" . "Mason, Christopher R." . "Hynek, Vladim\u00EDr" . "The preparation and characterization of novel PIM-1/silicalite-1 (MFI) mixed matrix membranes (MMMs) are reported. Silicalite-1 crystals of size 350 nm were synthesized and functionalized with 2-phenylethyl groups to favour a higher hydrophobicity in the PIM-1 matrix. MMMs with different functionalized crystal loadings (from 8.4 to 35.5 v%) were prepared, characterized and tested in the separation of ethanol from aqueous mixtures with different concentration (5 and 9 wt%) via pervaporation. Pure gas transport properties were also measured for the MMM with the highest filler loading. The enhancement in both ethanol/water separation factor (5.7 vs. 4.3) and CO2/N-2 selectivity (30 vs. 24) compared to neat PIM-1 indicates a positive effect of the silicalite-1 on the molecular separations investigated." . "Galiano, Francesco" . . "54" . "9"^^ . . "New organophilic mixed matrix membranes derived from a polymer of intrinsic microporosity and silicalite-1" . . . . "http://www.sciencedirect.com/science/article/pii/S0032386113001663" . . "Budd, Peter M." . "Friess, Karel" . . "Polymer" . "New organophilic mixed matrix membranes derived from a polymer of intrinsic microporosity and silicalite-1" . "000317632900002" . . . "New organophilic mixed matrix membranes derived from a polymer of intrinsic microporosity and silicalite-1"@en . "RIV/60461373:22340/13:43895273!RIV14-MSM-22340___" . "8"^^ . . "10.1016/j.polymer.2013.02.032" . "Buonomenna, Maria G." . . . "New organophilic mixed matrix membranes derived from a polymer of intrinsic microporosity and silicalite-1"@en . "91642" . "Mixed matrix membranes; Silicalite-1 (MFI) crystals; Polymer of intrinsic microporosity (PIM-1)"@en . . "The preparation and characterization of novel PIM-1/silicalite-1 (MFI) mixed matrix membranes (MMMs) are reported. Silicalite-1 crystals of size 350 nm were synthesized and functionalized with 2-phenylethyl groups to favour a higher hydrophobicity in the PIM-1 matrix. MMMs with different functionalized crystal loadings (from 8.4 to 35.5 v%) were prepared, characterized and tested in the separation of ethanol from aqueous mixtures with different concentration (5 and 9 wt%) via pervaporation. Pure gas transport properties were also measured for the MMM with the highest filler loading. The enhancement in both ethanol/water separation factor (5.7 vs. 4.3) and CO2/N-2 selectivity (30 vs. 24) compared to neat PIM-1 indicates a positive effect of the silicalite-1 on the molecular separations investigated."@en . "0032-3861" . "RIV/60461373:22340/13:43895273" . "Figoli, Alberto" . "[54ED4C4F07C7]" .