"From extraction experiments and gama-activity measurements, the extraction constant corresponding to the equilibrium Cs+ (aq) + A? (aq) + 1(nb) ? 1?Cs+(nb) + A?(nb) taking place in the two-phase water-nitrobenzene system (A? = picrate, 1 = dibenzo-30-crown-10; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log Kex (1?Cs+,A?) = 4.0 +- 0.1. Further, the stability constant of the 1?Cs+ complex in nitrobenzene saturated with water was calculated for a temperature of 25 \u00B0C: log betanb (1?Cs+) = 5.9 +- 0.1. Finally, by using quantum-mechanical DFT calculations, the most probable structure of the resulting cationic complex species 1?Cs+ was derived." . "[6BF3C2E1D6E5]" . "Experimental and theoretical study on the complexation of the cesium cation with dibenzo-30-crown-10" . "Toman, P." . "Journal of Radioanalytical and Nuclear Chemistry" . . "10.1007/s10967-011-1598-5" . . . "Makrl\u00EDk, Emanuel" . . . . . . . "RIV/60461373:22340/12:43893261!RIV13-MSM-22340___" . . . "RIV/60461373:22340/12:43893261" . "1"^^ . "Va\u0148ura, Petr" . . "0236-5731" . "4"^^ . "DE - Spolkov\u00E1 republika N\u011Bmecko" . "Experimental and theoretical study on the complexation of the cesium cation with dibenzo-30-crown-10"@en . . "3"^^ . . "292" . . . . . . . "3" . . "Experimental and theoretical study on the complexation of the cesium cation with dibenzo-30-crown-10"@en . "000305232400029" . "P(GAP205/10/2280), S, Z(AV0Z40500505)" . "From extraction experiments and gama-activity measurements, the extraction constant corresponding to the equilibrium Cs+ (aq) + A? (aq) + 1(nb) ? 1?Cs+(nb) + A?(nb) taking place in the two-phase water-nitrobenzene system (A? = picrate, 1 = dibenzo-30-crown-10; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log Kex (1?Cs+,A?) = 4.0 +- 0.1. Further, the stability constant of the 1?Cs+ complex in nitrobenzene saturated with water was calculated for a temperature of 25 \u00B0C: log betanb (1?Cs+) = 5.9 +- 0.1. Finally, by using quantum-mechanical DFT calculations, the most probable structure of the resulting cationic complex species 1?Cs+ was derived."@en . "Experimental and theoretical study on the complexation of the cesium cation with dibenzo-30-crown-10" . . "135538" . . "22340" . "DFT calculations; Stability constant; Nitrobenzene; Dibenzo-30-crown-10; Extraction; Picrate; Cesium"@en .