. . . "0021-9614" . . "000291522900020" . . "Gas-liquid partitioning coefficients (K_GL) were measured for halogenated volatile organic compounds (VOCs), namely 1-chlorobutane, methoxyflurane, pentafluoropropan-1-ol, heptafluorobutan-1-ol, alpha,alpha,alpha-trifluorotoluene, and toluene in aqueous solutions of natural alpha-, beta-, and gamma-cyclodextrins (CDs) at temperatures from (273.35 to 326.35) K employing the techniques of headspace gas chromatography and inert gas stripping. The binding constants of the 1:1 inclusion complex formation between the VOCs and CDs were evaluated from the depression of the VOCs volatility as a function of CD concentration. The host?guest size matching and the hydrophobic interaction concept were used to rationalize the observed widely different affinity of the VOC-CD pairs to form the inclusion complex. The enthalpic and entropic component of the standard Gibbs free energy of complex formation as derived from the temperature dependence of the binding constant indicate the thermodynamic origin of the binding to vary greatly among the systems studied, but follow the global enthalpy?entropy compensation relationships reported previously in the literature."@en . "Gas-liquid partitioning of halogenated volatile organic compounds in aqueous cyclodextrin solutions"@en . . . "[CE97C81A7F80]" . "3"^^ . . "Gas-liquid partitioning coefficients (K_GL) were measured for halogenated volatile organic compounds (VOCs), namely 1-chlorobutane, methoxyflurane, pentafluoropropan-1-ol, heptafluorobutan-1-ol, alpha,alpha,alpha-trifluorotoluene, and toluene in aqueous solutions of natural alpha-, beta-, and gamma-cyclodextrins (CDs) at temperatures from (273.35 to 326.35) K employing the techniques of headspace gas chromatography and inert gas stripping. The binding constants of the 1:1 inclusion complex formation between the VOCs and CDs were evaluated from the depression of the VOCs volatility as a function of CD concentration. The host?guest size matching and the hydrophobic interaction concept were used to rationalize the observed widely different affinity of the VOC-CD pairs to form the inclusion complex. The enthalpic and entropic component of the standard Gibbs free energy of complex formation as derived from the temperature dependence of the binding constant indicate the thermodynamic origin of the binding to vary greatly among the systems studied, but follow the global enthalpy?entropy compensation relationships reported previously in the literature." . "Gas-liquid partitioning of halogenated volatile organic compounds in aqueous cyclodextrin solutions" . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . "3"^^ . "Z(MSM6046137307)" . . "200820" . "Gas-liquid partitioning of halogenated volatile organic compounds in aqueous cyclodextrin solutions"@en . "Thermodynamic quantities of binding; Inclusion complex stability; Cyclodextrin; Water; VOC; Gas-liquid partitioning"@en . . . . . "22340" . "Journal of Chemical Thermodynamics" . "Gas-liquid partitioning of halogenated volatile organic compounds in aqueous cyclodextrin solutions" . "RIV/60461373:22340/11:43889946!RIV12-MSM-22340___" . "Bar\u00E1nkov\u00E1, Eva" . . "8" . "8"^^ . "Dohnal, Vladim\u00EDr" . "Ondo, Daniel" . . . "RIV/60461373:22340/11:43889946" . . . "10.1016/j.jct.2011.03.017" . . . "43" . .