. . "10.1016/j.molstruc.2010.11.019" . "Spectroscopic study of SERS- and SEIRA-activity of copper large-scaled surface substrates prepared by electrochemical deposition: What is the role of oxidation-reduction cycle treatment?"@en . "Kokaislov\u00E1, Al\u017Eb\u011Bta" . . . "000291066000064" . . . "RIV/60461373:22340/11:43877195!RIV12-MSM-22340___" . . "Spectroscopic study of SERS- and SEIRA-activity of copper large-scaled surface substrates prepared by electrochemical deposition: What is the role of oxidation-reduction cycle treatment?" . . "0022-2860" . . "RIV/60461373:22340/11:43877195" . . "6"^^ . "22340" . . "\u010Cejkov\u00E1, Jitka" . "Spectroscopic study of SERS- and SEIRA-activity of copper large-scaled surface substrates prepared by electrochemical deposition: What is the role of oxidation-reduction cycle treatment?"@en . . "6"^^ . . . "Mat\u011Bjka, Pavel" . "993" . "[D3AA389C400F]" . "1" . . "Journal of Molecular Structure" . "10"^^ . . . . "NL - Nizozemsko" . "231393" . . "\u010Clupek, Martin" . . "Principal component analysis (PCA); Scanning Electron Microscopy (SEM); Diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS); Surface-enhanced infrared absorption (SEIRA); Surface-enhanced Raman scattering (SERS)"@en . "Prokopec, Vadym" . "P(GD104/08/H055), S, Z(MSM6046137306), Z(MSM6046137307)" . "Dendisov\u00E1, Marcela" . . . . . . . "Spectroscopic study of SERS- and SEIRA-activity of copper large-scaled surface substrates prepared by electrochemical deposition: What is the role of oxidation-reduction cycle treatment?" . "Surface-enhanced Raman scattering (SERS) and surface-enhanced infrared absorption (SEIRA) are powerful analytical techniques used for the study and characterization of ultrathin films and monolayers of organic compounds adsorbed on the nanostructured surface of several metals. The main requirement which has to be met for the SERS- and SEIRA-activity is the proper morphology of the surface in nano-scale, which can be tailored by the preparation procedure. In the present work different electrochemical preparation procedures of copper substrates (cathodic reduction from electrochemical baths or its combination with oxidation-reduction cycles (ORC) treatment) were developed with the aim of fabrication of the substrate with both SERS- and SEIRA-activity for the selected model analyte. The diffuse reflectance methodology was designed to study SEIRA-activity on large-scaled nanostructured surfaces. The nanostructure of the copper surface was characterized using Scanning Electron Microscopy (SEM)."@en . "Surface-enhanced Raman scattering (SERS) and surface-enhanced infrared absorption (SEIRA) are powerful analytical techniques used for the study and characterization of ultrathin films and monolayers of organic compounds adsorbed on the nanostructured surface of several metals. The main requirement which has to be met for the SERS- and SEIRA-activity is the proper morphology of the surface in nano-scale, which can be tailored by the preparation procedure. In the present work different electrochemical preparation procedures of copper substrates (cathodic reduction from electrochemical baths or its combination with oxidation-reduction cycles (ORC) treatment) were developed with the aim of fabrication of the substrate with both SERS- and SEIRA-activity for the selected model analyte. The diffuse reflectance methodology was designed to study SEIRA-activity on large-scaled nanostructured surfaces. The nanostructure of the copper surface was characterized using Scanning Electron Microscopy (SEM)." . .