. . "Praha" . "[AE64F24D2B8F]" . . . "Termodynamika 2005" . "22340" . "3"^^ . "alkanol; dissolution; generalized description"@en . "A generalized picture of the dissolution energetics for alkanols in water has been proposed. Two scaling parameters, namely the maximum value of the limiting activity coefficient and the temperature where this maximum occurs are used as solute characteristics to define reduced quantities. Using these dimensionless quantities, a universal pattern of dissolution behavior has been convincingly demonstrated for 1-alkanols (C1-C5) and branched alkanols (C3-C4) in generalized plots of various dissolution properties (limiting activity coefficient, enthalpy, entropy, heat capacity) over the temperature range from 273 to 373 K (reduced temperatures from 0.70 to 1.15). An equation for the generalized analytical description of alkanols dissolution energetics has been developed and its very good performance proved." . "RIV/60461373:22340/05:00014644!RIV06-MSM-22340___" . "A generalized picture of the dissolution energetics for alkanols in water has been proposed. Two scaling parameters, namely the maximum value of the limiting activity coefficient and the temperature where this maximum occurs are used as solute characteristics to define reduced quantities. Using these dimensionless quantities, a universal pattern of dissolution behavior has been convincingly demonstrated for 1-alkanols (C1-C5) and branched alkanols (C3-C4) in generalized plots of various dissolution properties (limiting activity coefficient, enthalpy, entropy, heat capacity) over the temperature range from 273 to 373 K (reduced temperatures from 0.70 to 1.15). An equation for the generalized analytical description of alkanols dissolution energetics has been developed and its very good performance proved."@en . . "Towards the generalized thermodynamic description of dissolution of alcohols in water" . "Na cest\u011B ke generalizovan\u00E9mu termodynamick\u00E9mu popisu procesu rozpou\u0161t\u011Bn\u00ED alkanol\u016F ve vod\u011B"@cs . . . "546971" . "80-86238-49-0" . "Towards the generalized thermodynamic description of dissolution of alcohols in water" . "Byl navr\u017Een generalizovan\u00FD pohled na rozpou\u0161t\u011Bn\u00ED alkanol\u016F ve vod\u011B. K definici redukovan\u00FDch veli\u010Din byly pou\u017Eity dva parametry charakterizuj\u00EDc\u00ED p\u0159\u00EDslu\u0161n\u00FD alkanol - maxim\u00E1ln\u00ED hodnota limitn\u00EDho aktivitn\u00EDho koeficientu a teplota tohoto maxima. Pomoc\u00ED t\u011Bchto bezrozm\u011Brn\u00FDch veli\u010Din bylo p\u0159esv\u011Bd\u010Div\u011B demonstrov\u00E1no univerz\u00E1ln\u00ED sch\u00E9ma rozpou\u0161t\u011Bn\u00ED 1-alkanol\u016F (C1-C5) a v\u011Btven\u00FDch alkanol\u016F (C3-C4) ve vod\u011B v teplotn\u00EDm intervalu od 273 do 373 K (redukovan\u00E1 teplota od 0,70 do 1,15) prost\u0159ednictv\u00EDm generalizovan\u00FDch graf\u016F r\u016Fzn\u00FDch rozpou\u0161t\u011Bc\u00EDch vlastnost\u00ED (limitn\u00ED aktivitn\u00ED koeficient, enthalpie, entropie, tepeln\u00E1 kapacita). Byla navr\u017Eena analytick\u00E1 rovnice pro generalizovan\u00FD popis energetiky rozpou\u0161t\u011Bn\u00ED alkanol\u016F."@cs . "2005-09-16+02:00"^^ . "\u010Cesk\u00E1 spole\u010Dnost chemick\u00E1" . "Na cest\u011B ke generalizovan\u00E9mu termodynamick\u00E9mu popisu procesu rozpou\u0161t\u011Bn\u00ED alkanol\u016F ve vod\u011B"@cs . . . . "Towards the generalized thermodynamic description of dissolution of alcohols in water"@en . "59-61" . . "Brejlov" . "1"^^ . . "1"^^ . . . . . "Towards the generalized thermodynamic description of dissolution of alcohols in water"@en . "RIV/60461373:22340/05:00014644" . "Z(MSM6046137307)" . "Dohnal, Vladim\u00EDr" .