. . "RIV/60461373:22330/12:43894609" . "Cihelkov\u00E1, Kl\u00E1ra" . "978-80-86238-93-7" . . . "Oxidative reations - hydroperoxides of sterols and chemical kinetics"@en . . . "Z(MSM6046137305)" . . . "Sborn\u00EDk p\u0159edn\u00E1\u0161ek 50. mezin\u00E1rodn\u00ED konference o olej\u00EDch a tuc\u00EDch" . . . "22330" . . "\u010Cesk\u00E1 spole\u010Dnost chemick\u00E1" . "Cholesterol rozpu\u0161t\u011Bn\u00FD v lipidech podl\u00E9h\u00E1 za vysok\u00FDch teplot (100 - 200 \u00B0C) a za p\u0159\u00EDstupu vzduchu oxida\u010Dn\u00EDm a degrada\u010Dn\u00EDm reakc\u00EDm. V po\u010Date\u010Dn\u00ED f\u00E1zi autooxidace lipid\u016F by m\u011Bly b\u00FDt p\u0159\u00EDtomny hydroperoxidy sterol\u016F, kter\u00E9 se za podm\u00EDnek metody p\u0159i zm\u00FDdeln\u011Bn\u00ED za studena mohou stabilizovat p\u0159es alkoxidov\u00FD radik\u00E1l na \u0159adu sekund\u00E1rn\u00EDch oxida\u010Dn\u00EDch produkt\u016F. D\u016Fsledkem je nep\u0159esn\u00E9 stanoven\u00ED oxida\u010Dn\u00EDch produkt\u016F cholesterolu. Dal\u0161\u00EDm c\u00EDlem studie bylo srovn\u00E1n\u00ED reaktivity voln\u00FDch a v\u00E1zan\u00FDch sterol\u016F."@cs . "Cholesterol in lipids oxidizes and degrades under high temperatures (100 -200 \u00B0C) and under air access. In the initial phase of lipid autoxidation steryl hydroperoxides should be presented that can be stabilized to secondary oxidative products under method conditions (saponification) through alkoxide radical. The result is that determination of oxidative cholesterol products of cholesterol is inaccurate. Other aim of this study was to compare of reactivity of free and bounded sterols."@en . "4"^^ . "RIV/60461373:22330/12:43894609!RIV13-MSM-22330___" . . "6"^^ . . "157538" . . "[B0825EDD0C3A]" . . "Oxida\u010Dn\u00ED reakce - hydroperoxidy sterol\u016F a chemick\u00E1 kinetika"@cs . . "4"^^ . . "Precov\u00E1, Radovana" . "Kyselka, Jan" . . . "Oxida\u010Dn\u00ED reakce - hydroperoxidy sterol\u016F a chemick\u00E1 kinetika" . "Filip, Vladim\u00EDr" . "Praha" . "2012-05-16+02:00"^^ . "oxidation; hydroperoxides; sterols"@en . "Str\u00E1\u017Enice" . "Oxida\u010Dn\u00ED reakce - hydroperoxidy sterol\u016F a chemick\u00E1 kinetika"@cs . . "Cholesterol rozpu\u0161t\u011Bn\u00FD v lipidech podl\u00E9h\u00E1 za vysok\u00FDch teplot (100 - 200 \u00B0C) a za p\u0159\u00EDstupu vzduchu oxida\u010Dn\u00EDm a degrada\u010Dn\u00EDm reakc\u00EDm. V po\u010Date\u010Dn\u00ED f\u00E1zi autooxidace lipid\u016F by m\u011Bly b\u00FDt p\u0159\u00EDtomny hydroperoxidy sterol\u016F, kter\u00E9 se za podm\u00EDnek metody p\u0159i zm\u00FDdeln\u011Bn\u00ED za studena mohou stabilizovat p\u0159es alkoxidov\u00FD radik\u00E1l na \u0159adu sekund\u00E1rn\u00EDch oxida\u010Dn\u00EDch produkt\u016F. D\u016Fsledkem je nep\u0159esn\u00E9 stanoven\u00ED oxida\u010Dn\u00EDch produkt\u016F cholesterolu. Dal\u0161\u00EDm c\u00EDlem studie bylo srovn\u00E1n\u00ED reaktivity voln\u00FDch a v\u00E1zan\u00FDch sterol\u016F." . "Oxidative reations - hydroperoxides of sterols and chemical kinetics"@en . "Oxida\u010Dn\u00ED reakce - hydroperoxidy sterol\u016F a chemick\u00E1 kinetika" .