"RIV/60461373:22330/10:00024213" . "248809" . "000280033500020" . "Chemistry and Physics of Lipids" . . "22330" . "23"^^ . "RIV/60461373:22330/10:00024213!RIV11-MSM-22330___" . . . . . "The binary phase behavior of 1,3-dilauroyl-2-stearoyl-sn-glycerol and 1,2-dilauroyl-3-stearoyl-sn-glycerol" . "The binary phase behavior of 1,3-dilauroyl-2-stearoyl-sn-glycerol and 1,2-dilauroyl-3-stearoyl-sn-glycerol"@en . . "Filip, Vladim\u00EDr" . "[A9141A31C15F]" . . "IE - Irsko" . . . "The binary phase behavior of purified 1,3-dilauroyl-2-stearoyl-sn-glycerol (LSL) and 1,2-dilauroyl-3-stearoyl-sn-glycerol (LLS) was investigated at a slow and a relatively fast cooling rate in terms of melting and crystallization, polymorphism, solid fat content (SFC), hardness and microstructure. Much of the behavior of the system is explained by its polymorphism and the influence of thermal processing. The measured trends in structural characteristics, thermal properties, SFC, relative hardness and microstructure delimit three groups of mixtures which imply a competition between the stabilizing effect of LSL and disordering introduced by kinetic effects: (a) LLS-rich mixtures with LSL molar fractions (XLSL) less than 0.3, (b) mixtures with XLSL clustered around 0.5 and (c) LSL-rich mixtures with XLSL >= 0.7. The balance between ordering and kinetic effects determines the polymorphism of the mixtures, which in turn determines the behavior of the LSL/LLS system. The kinetic phase diagram of the LSL" . . . "0009-3084" . . "6" . "The binary phase behavior of purified 1,3-dilauroyl-2-stearoyl-sn-glycerol (LSL) and 1,2-dilauroyl-3-stearoyl-sn-glycerol (LLS) was investigated at a slow and a relatively fast cooling rate in terms of melting and crystallization, polymorphism, solid fat content (SFC), hardness and microstructure. Much of the behavior of the system is explained by its polymorphism and the influence of thermal processing. The measured trends in structural characteristics, thermal properties, SFC, relative hardness and microstructure delimit three groups of mixtures which imply a competition between the stabilizing effect of LSL and disordering introduced by kinetic effects: (a) LLS-rich mixtures with LSL molar fractions (XLSL) less than 0.3, (b) mixtures with XLSL clustered around 0.5 and (c) LSL-rich mixtures with XLSL >= 0.7. The balance between ordering and kinetic effects determines the polymorphism of the mixtures, which in turn determines the behavior of the LSL/LLS system. The kinetic phase diagram of the LSL"@en . "5"^^ . "The binary phase behavior of 1,3-dilauroyl-2-stearoyl-sn-glycerol and 1,2-dilauroyl-3-stearoyl-sn-glycerol" . "binary phase behavior; symmetrical and asymmetrical triacylglycerols; polymorphism; crystallization; microstructure; crystal network; differential scanning calorimetry"@en . . "Narine, S. S." . "The binary phase behavior of 1,3-dilauroyl-2-stearoyl-sn-glycerol and 1,2-dilauroyl-3-stearoyl-sn-glycerol"@en . . . "K\u016Ftek, Tom\u00E1\u0161" . "Bouzidi, L." . . "Boodhooa, M. V." . . . "Z(MSM6046137305)" . "163" . . . "2"^^ .