"Synthesis of functionalized phenyl, 2-thienyl, and N-methyl-pyrrol-2-yl Fischer carbene complexes of chromium and tungsten was achieved via a Negishi cross-coupling reaction of metalated aminocarbenes in the presence of a palladium catalyst. The reverse approach, i.e., coupling bromocarbenes with organozinc reagents, is also feasible and is particularly useful with alkoxycarbene complexes, metalation of which is not possible. Both these procedures are also suitable for the cross-coupling of molybdenum amino- and alkoxycarbene complexes. The presented methodology enables an access to the new amino and alkoxy carbene complexes bearing aldehyde, ketone, nitrile, and ester functionality." . "P(LC06070)" . "RIV/60461373:22310/14:43898141" . "Organometallics" . . "33" . "10.1021/om500925m" . "22310" . . "Synthesis of functionalized phenyl, 2-thienyl, and N-methyl-pyrrol-2-yl Fischer carbene complexes of chromium and tungsten was achieved via a Negishi cross-coupling reaction of metalated aminocarbenes in the presence of a palladium catalyst. The reverse approach, i.e., coupling bromocarbenes with organozinc reagents, is also feasible and is particularly useful with alkoxycarbene complexes, metalation of which is not possible. Both these procedures are also suitable for the cross-coupling of molybdenum amino- and alkoxycarbene complexes. The presented methodology enables an access to the new amino and alkoxy carbene complexes bearing aldehyde, ketone, nitrile, and ester functionality."@en . "Dvo\u0159\u00E1k, Dalimil" . "Jur\u00E1skov\u00E1, Ivana" . "22" . . . . . "RHODIUM(I); 3+2 CYCLIZATION; FISCHER CARBENES; INTERNAL ALKYNES; AMINOCARBENE COMPLEXES; CATALYZED DIMERIZATION; ORGANIC-SYNTHESIS; SELF-DIMERIZATION; RING-CLOSING METATHESIS; TRANSITION-METAL COMPLEXES"@en . . "000345552500039" . "3"^^ . . "Negishi cross-coupling reaction as a simple and efficient route to functionalized amino and alkoxy carbene complexes of chromium, molybdenum, and tungsten." . "31953" . "3"^^ . . . "0276-7333" . "11"^^ . "Negishi cross-coupling reaction as a simple and efficient route to functionalized amino and alkoxy carbene complexes of chromium, molybdenum, and tungsten."@en . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . . . "RIV/60461373:22310/14:43898141!RIV15-MSM-22310___" . . . . . . . . . "[D476F2C637F9]" . "Negishi cross-coupling reaction as a simple and efficient route to functionalized amino and alkoxy carbene complexes of chromium, molybdenum, and tungsten." . . "Negishi cross-coupling reaction as a simple and efficient route to functionalized amino and alkoxy carbene complexes of chromium, molybdenum, and tungsten."@en . . . . "Tobrman, Tom\u00E1\u0161" .