. "Molecules" . "V\u00E1clav\u00EDk, Ji\u0159\u00ED" . "Experimental and Theoretical Perspectives of the Noyori-Ikariya Asymmetric Transfer Hydrogenation of Imines" . . . "http://dx.doi.org/10.3390/molecules19066987" . "Experimental and Theoretical Perspectives of the Noyori-Ikariya Asymmetric Transfer Hydrogenation of Imines"@en . . "6" . "Matu\u0161ka, Ond\u0159ej" . "Pech\u00E1\u010Dek, Jan" . "[BBB8C4820045]" . "The asymmetric transfer hydrogenation (ATH) of imines catalyzed by the Noyori-Ikariya [RuCl(\u00E9ta6-arene)(N-arylsulfonyl-DPEN)] (DPEN = 1,2-diphenylethylene-1,2-diamine) half-sandwich complexes is a research topic that is still being intensively developed. This article focuses on selected aspects of this catalytic system. First, a great deal of attention is devoted to the N-arylsulfonyl moiety of the catalysts in terms of its interaction with protonated imines (substrates) and amines (components of the hydrogen-donor mixture). The second part is oriented toward the role of the \u00E9ta6-coordinated arene. The final part concerns the imine substrate structural modifications and their importance in connection with ATH. Throughout the text, the summary of known findings is complemented with newly-presented ones, which have been approached both experimentally and computationally." . . . "Ka\u010Der, Petr" . "Experimental and Theoretical Perspectives of the Noyori-Ikariya Asymmetric Transfer Hydrogenation of Imines"@en . "\u0160ot, Petr" . . . "21"^^ . "P(GAP106/12/1276), P(LO1215)" . . "15793" . "DFT; arene; sulfonyl; ligand; imine; asymmetric hydrogenation; ruthenium"@en . . "CH - \u0160v\u00FDcarsk\u00E1 konfederace" . "Kuzma, Marek" . "6"^^ . "7"^^ . . . . "RIV/60461373:22310/14:43897963!RIV15-GA0-22310___" . . . . "22310" . "RIV/60461373:22310/14:43897963" . . . "Vilhanov\u00E1, Be\u00E1ta" . . "1420-3049" . "000338586700006" . . . "19" . "The asymmetric transfer hydrogenation (ATH) of imines catalyzed by the Noyori-Ikariya [RuCl(\u00E9ta6-arene)(N-arylsulfonyl-DPEN)] (DPEN = 1,2-diphenylethylene-1,2-diamine) half-sandwich complexes is a research topic that is still being intensively developed. This article focuses on selected aspects of this catalytic system. First, a great deal of attention is devoted to the N-arylsulfonyl moiety of the catalysts in terms of its interaction with protonated imines (substrates) and amines (components of the hydrogen-donor mixture). The second part is oriented toward the role of the \u00E9ta6-coordinated arene. The final part concerns the imine substrate structural modifications and their importance in connection with ATH. Throughout the text, the summary of known findings is complemented with newly-presented ones, which have been approached both experimentally and computationally."@en . . . "Experimental and Theoretical Perspectives of the Noyori-Ikariya Asymmetric Transfer Hydrogenation of Imines" . . "10.3390/molecules19066987" . .