"Journal of Fluorine Chemistry" . . . . . "Kv\u00ED\u010Dala, Jaroslav" . . . "131" . . "6"^^ . . . . . "Kv\u00ED\u010Dalov\u00E1, Magdalena" . . . "Paterov\u00E1, Jana" . . "12" . . "0022-1139" . "Perfluoroalkyl iodide; Perfluoroalkylmagnesium; Fluoro Grignard reagent; Cyclic sulfate; Nucleophilic substitution; Fluoroalkyl sulfate; Fluoroalcohol; DFT"@en . "3"^^ . "Skalick\u00FD, Martin" . "291556" . . "Ryb\u00E1\u010Dkov\u00E1, Mark\u00E9ta" . "22310" . . "6"^^ . "Cva\u010Dka, Josef" . . . "RIV/60461373:22310/10:00023632!RIV11-GA0-22310___" . "CH - \u0160v\u00FDcarsk\u00E1 konfederace" . . . . "[36C2AE4C9D11]" . "Synthesis of 2-(perfluoroalkyl)ethyl potassium sulfates based on perfluorinated Grignard reagents" . . "The first example of nucleophilic substitution with perfluoroalkyl Grignard reagents on the sp3 carbon centre is described. Thus, a series of organometals RF-MgBr, prepared from perfluorinated alkyl iodides RF-I with RF = C4F9, C6F13, C8F17, C10F21 and C12F25, reacted with 1,3,2-dioxathiolane-2,2-dioxide to afford the corresponding 2-(perfluoroalkyl)ethyl magnesium sulfates, which were isolated after metathesis to the corresponding potassium salts. In the model reaction, perfluorohexylmagnesium iodide was reacted with methyl triflate yielding polyfluorinated alkane." . "Synthesis of 2-(perfluoroalkyl)ethyl potassium sulfates based on perfluorinated Grignard reagents"@en . "The first example of nucleophilic substitution with perfluoroalkyl Grignard reagents on the sp3 carbon centre is described. Thus, a series of organometals RF-MgBr, prepared from perfluorinated alkyl iodides RF-I with RF = C4F9, C6F13, C8F17, C10F21 and C12F25, reacted with 1,3,2-dioxathiolane-2,2-dioxide to afford the corresponding 2-(perfluoroalkyl)ethyl magnesium sulfates, which were isolated after metathesis to the corresponding potassium salts. In the model reaction, perfluorohexylmagnesium iodide was reacted with methyl triflate yielding polyfluorinated alkane."@en . "P(GA203/06/1511), P(LC06070), Z(AV0Z40320502), Z(AV0Z40550506), Z(MSM6046137301)" . "RIV/60461373:22310/10:00023632" . . "Synthesis of 2-(perfluoroalkyl)ethyl potassium sulfates based on perfluorinated Grignard reagents" . "000285899700009" . . "Synthesis of 2-(perfluoroalkyl)ethyl potassium sulfates based on perfluorinated Grignard reagents"@en . . .