"3" . . . "10.1007/s10973-013-3025-3" . . . "HU - Ma\u010Farsko" . . . "1388-6150" . . "Journal of Thermal Analysis and Calorimetry" . . "Holba, Pavel" . "P(ED2.1.00/03.0088)" . "Heat inertia and temperature gradient in the treatment of DTA peaks. Existing on every occasion of real measurements but until now omitted."@en . . . "11"^^ . "\u0160est\u00E1k, Jaroslav" . . . "2"^^ . . "[38A7038561B6]" . . . "RIV/49777513:23640/13:43920747" . "Heat inertia and temperature gradient in the treatment of DTA peaks. Existing on every occasion of real measurements but until now omitted." . . . "2"^^ . "RIV/49777513:23640/13:43920747!RIV14-MSM-23640___" . . . "Non-isothermal kinetics; Quantitative evaluation; Temperature gradient; Peak rectification; Heat inertia effect; Curve distortion; DTA theory; Thermal analysis; History"@en . "Heat inertia and temperature gradient in the treatment of DTA peaks. Existing on every occasion of real measurements but until now omitted."@en . "Heat inertia and temperature gradient in the treatment of DTA peaks. Existing on every occasion of real measurements but until now omitted." . . . "113" . . "Historical development of methods and theoretical basis of differential thermal analysis (DTA) are outlined. The measured difference Delta T is not directly proportional to the rate of the process (d alpha/dt) but includes also the effect of heat inertia proportional to the slope d Delta T/dt as it was derived and incorporated into DTA equation by Vold (Anal Chem 21:683-688, 1949), Borchardt and Daniels (J Am Chem Soc 79:41-46, 1957), and suggested to be corrected in the authors' previous papers (1976). DTA experiments with rectangular pulses realized by micro-heater inside the sample show that the correction of DTA signal employing calculated heat inertia term of the DTA equation is reliable but not yet fully sufficient. It was a reason to derive a more complete DTA equation including a term expressing the changes in the temperature field inside the sample during process.. Itemized 150 references with titles." . "23640" . "77158" . "Historical development of methods and theoretical basis of differential thermal analysis (DTA) are outlined. The measured difference Delta T is not directly proportional to the rate of the process (d alpha/dt) but includes also the effect of heat inertia proportional to the slope d Delta T/dt as it was derived and incorporated into DTA equation by Vold (Anal Chem 21:683-688, 1949), Borchardt and Daniels (J Am Chem Soc 79:41-46, 1957), and suggested to be corrected in the authors' previous papers (1976). DTA experiments with rectangular pulses realized by micro-heater inside the sample show that the correction of DTA signal employing calculated heat inertia term of the DTA equation is reliable but not yet fully sufficient. It was a reason to derive a more complete DTA equation including a term expressing the changes in the temperature field inside the sample during process.. Itemized 150 references with titles."@en . "000323503300080" . .