. . "Kolsk\u00E1, Zde\u0148ka" . . "Heat capacity of liquids: database of recommended values and estimation by a group contribution method"@en . . . "P(IAA400720710), Z(MSM 223300006), Z(MSM6046137307)" . . . "\u010Cesk\u00E1 spole\u010Dnost chemick\u00E9ho in\u017Een\u00FDrstv\u00ED" . . "Kukal, Jarom\u00EDr" . "RIV/44555601:13440/07:00003815" . . "CHISA 2007 Sborn\u00EDk" . "1"^^ . . "80-86059-47-2" . . "R\u016F\u017Ei\u010Dka, Vlastimil" . "Z\u00E1bransk\u00FD, Milan" . "Praha" . "V r\u00E1mci tohoto projektu byla aktualizov\u00E1na a roz\u0161\u00ED\u0159ena datab\u00E1ze doporu\u010Den\u00FDch dat tepeln\u00FDch kapacit kapalin , kter\u00E1 byla p\u016Fvodn\u011B vytvo\u0159ena pro t\u00E9m\u011B\u0159 2000 l\u00E1tek. Byla nov\u011B vlo\u017Eena experiment\u00E1ln\u00ED data pro 416 \u010Dist\u00FDch kapalin, kter\u00E9 maj\u00ED teplotu t\u00E1n\u00ED do 573 K, a kter\u00E1 byla publikov\u00E1na v literatu\u0159e v letech 2000 a\u017E 2006. Zahrnuty byly hodnoty p\u0159ev\u00E1\u017En\u011B pro organick\u00E9 l\u00E1tky. Nov\u011B byla vlo\u017Eena data pro skupinu 50 iontov\u00FDch kapalin. Sou\u010Dasn\u00E1 datab\u00E1ze doporu\u010Den\u00FDch dat byla pou\u017Eita k modifikaci strukturn\u011B p\u0159\u00EDsp\u011Bvkov\u00E9 metody pro predikci tepeln\u00FDch kapacit kapalin v z\u00E1vislosti na teplot\u011B. Nov\u011B vznikl\u00FD model je kombinac\u00ED p\u016Fvodn\u00ED t\u0159\u00ED\u00FArov\u0148ov\u00E9 p\u0159\u00EDsp\u011Bvkov\u00E9 metody Marrera a Ganiho a vztahu pro teplotn\u00ED z\u00E1vislost tepeln\u00E9 kapacity. Tento model byl testov\u00E1n pro sadu 549 l\u00E1tek ze st\u00E1vaj\u00EDc\u00ED datab\u00E1ze pro t\u0159i p\u0159\u00EDpady: a) tzv. hierarchick\u00FD p\u0159\u00EDstup, ve kter\u00E9m se parametry prvn\u00ED, druh\u00E9 a t\u0159et\u00ED \u00FArovn\u011B odhadu po\u010D\u00EDtaj\u00ED ve t\u0159ech n\u00E1sleduj\u00EDc\u00EDch kroc\u00EDch (nastaviteln\u00FD parametr je po\u010D\u00EDt\u00E1n pouze v prvn\u00EDm kroku); b) pro podobn\u00FD postup, j"@cs . "Tepeln\u00E9 kapacity \u010Dist\u00FDch l\u00E1tek - datab\u00E1ze a odhady pomoc\u00ED strukturn\u011B p\u0159\u00EDsp\u011Bvkov\u00FDch metod"@cs . "V r\u00E1mci tohoto projektu byla aktualizov\u00E1na a roz\u0161\u00ED\u0159ena datab\u00E1ze doporu\u010Den\u00FDch dat tepeln\u00FDch kapacit kapalin , kter\u00E1 byla p\u016Fvodn\u011B vytvo\u0159ena pro t\u00E9m\u011B\u0159 2000 l\u00E1tek. Byla nov\u011B vlo\u017Eena experiment\u00E1ln\u00ED data pro 416 \u010Dist\u00FDch kapalin, kter\u00E9 maj\u00ED teplotu t\u00E1n\u00ED do 573 K, a kter\u00E1 byla publikov\u00E1na v literatu\u0159e v letech 2000 a\u017E 2006. Zahrnuty byly hodnoty p\u0159ev\u00E1\u017En\u011B pro organick\u00E9 l\u00E1tky. Nov\u011B byla vlo\u017Eena data pro skupinu 50 iontov\u00FDch kapalin. Sou\u010Dasn\u00E1 datab\u00E1ze doporu\u010Den\u00FDch dat byla pou\u017Eita k modifikaci strukturn\u011B p\u0159\u00EDsp\u011Bvkov\u00E9 metody pro predikci tepeln\u00FDch kapacit kapalin v z\u00E1vislosti na teplot\u011B. Nov\u011B vznikl\u00FD model je kombinac\u00ED p\u016Fvodn\u00ED t\u0159\u00ED\u00FArov\u0148ov\u00E9 p\u0159\u00EDsp\u011Bvkov\u00E9 metody Marrera a Ganiho a vztahu pro teplotn\u00ED z\u00E1vislost tepeln\u00E9 kapacity. Tento model byl testov\u00E1n pro sadu 549 l\u00E1tek ze st\u00E1vaj\u00EDc\u00ED datab\u00E1ze pro t\u0159i p\u0159\u00EDpady: a) tzv. hierarchick\u00FD p\u0159\u00EDstup, ve kter\u00E9m se parametry prvn\u00ED, druh\u00E9 a t\u0159et\u00ED \u00FArovn\u011B odhadu po\u010D\u00EDtaj\u00ED ve t\u0159ech n\u00E1sleduj\u00EDc\u00EDch kroc\u00EDch (nastaviteln\u00FD parametr je po\u010D\u00EDt\u00E1n pouze v prvn\u00EDm kroku); b) pro podobn\u00FD postup, j" . "RIV/44555601:13440/07:00003815!RIV08-AV0-13440___" . "liquid heat capacity; database; recommended data; estimation; group contribution method"@en . "[CA2D3BB2425F]" . . . . "Heat capacity of liquids: database of recommended values and estimation by a group contribution method"@en . "Tepeln\u00E9 kapacity \u010Dist\u00FDch l\u00E1tek - datab\u00E1ze a odhady pomoc\u00ED strukturn\u011B p\u0159\u00EDsp\u011Bvkov\u00FDch metod" . . . . "166" . . . "Tepeln\u00E9 kapacity \u010Dist\u00FDch l\u00E1tek - datab\u00E1ze a odhady pomoc\u00ED strukturn\u011B p\u0159\u00EDsp\u011Bvkov\u00FDch metod" . . "1"^^ . "Databases that contain recommended data on liquid heat capacities for almost 2000 mostly organic compounds were updated and extended. Experimental data on heat capacities of 411 pure liquid organic and some inorganic compounds that have melting temperature below 573 K, as well as of 50 ionic liquids, published in the primary literature between 2000 and 2006, were compiled and critically evaluated. Recommended values supplemented with an assessment of their uncertainty and presented in terms of parameters of correlating equations for temperature dependence of heat capacities will be provided by the end of 2007 as a report to the IUPAC project. Current database of recommended values was used to extend the group contribution method to predict heat capacity of liquids as a function of temperature. The model development entailed a combination of the method by Marrero and Gani and a relation for the temperature dependence of heat capacity."@en . "4"^^ . "Tepeln\u00E9 kapacity \u010Dist\u00FDch l\u00E1tek - datab\u00E1ze a odhady pomoc\u00ED strukturn\u011B p\u0159\u00EDsp\u011Bvkov\u00FDch metod"@cs . "454641" . "13440" .