. . "Chemick\u00E9 listy" . "26310" . . "Low molecular weight alpha-allyl terminated poly(tert-butyl methacrylate) (poly(t-BMA)) macromonomers with narrow polydispersities (Mw/Mn = 1.16) were synthesized via controlled atom transfer radical polymerization (ATRP) using Cu(I)Br/hexamethyltriethylenetetraamine catalyst system in conjunction with an allyl-2-bromoisobutyrate as the functional initiator. The polymerizations exhibited a linear increase of molecular weight in direct proportion to the monomer conversion and a first-order kinetics with respect to monomer concentration (GPC and GC analysis). No significant difference was found between using polar or non-polar solvents (tetrahydrofuran or benzene, respectively). Optimization of reaction conditions with a view to obtain the highest degree of active terminal bromine is discussed. Quenching the ATRP reaction with allyltributyltin afforded alpha,omega-allyl terminated poly(t-BMA) macromonomers by replacing of the terminal bromine for omega-allyl functional group. Successful synthetic steps" . "CZ - \u010Cesk\u00E1 republika" . . "0009-2770" . "RIV/00216305:26310/02:PU38986!RIV11-MSM-26310___" . . "Koberstein, Jeffrey T." . "637140" . . "macromonomers, biomaterial, poly(methacrylic acid)"@en . . . "A novel well-defined linear poly(methacrylic acid) macromonomers for biomaterial applications: The synthesis and characterization"@en . "5"^^ . "[6E83CE5A307D]" . . "Turro, Nicholas" . "symposia" . "A novel well-defined linear poly(methacrylic acid) macromonomers for biomaterial applications: The synthesis and characterization" . . . . "Vojtov\u00E1, Lucy" . "RIV/00216305:26310/02:PU38986" . . "1"^^ . . "3"^^ . "96(S)" . "N, V, Z(MSM 263100019)" . "A novel well-defined linear poly(methacrylic acid) macromonomers for biomaterial applications: The synthesis and characterization"@en . . "Low molecular weight alpha-allyl terminated poly(tert-butyl methacrylate) (poly(t-BMA)) macromonomers with narrow polydispersities (Mw/Mn = 1.16) were synthesized via controlled atom transfer radical polymerization (ATRP) using Cu(I)Br/hexamethyltriethylenetetraamine catalyst system in conjunction with an allyl-2-bromoisobutyrate as the functional initiator. The polymerizations exhibited a linear increase of molecular weight in direct proportion to the monomer conversion and a first-order kinetics with respect to monomer concentration (GPC and GC analysis). No significant difference was found between using polar or non-polar solvents (tetrahydrofuran or benzene, respectively). Optimization of reaction conditions with a view to obtain the highest degree of active terminal bromine is discussed. Quenching the ATRP reaction with allyltributyltin afforded alpha,omega-allyl terminated poly(t-BMA) macromonomers by replacing of the terminal bromine for omega-allyl functional group. Successful synthetic steps"@en . . . "A novel well-defined linear poly(methacrylic acid) macromonomers for biomaterial applications: The synthesis and characterization" .