"RIV/00216275:25310/14:39898158" . "000343329100073" . "P(GBP106/12/G015)" . "Combined microcalorimetric and IR spectroscopic study on carbon dioxide adsorption in H-MCM-22"@en . "Bul\u00E1nek, Roman" . "7813" . "Delgado, M. R." . . "Arean, C. O." . . "The thermodynamics of carbon dioxide adsorption in the protonic zeolite H-MCM-22 (Si:Al = 16:1) was investigated by means of adsorption calorimetry and variable-temperature IR spectroscopy, a technique that affords determination of standard adsorption enthalpy (Delta H-0) and entropy (Delta S-0) from analysis of a series of IR spectra recorded over a temperature range while simultaneously measuring equilibrium pressure inside a closed IR cell. Delta H-0 resulted to be -24.5 (+/- 2) kJ mol(-1), while for the entropy change the value of Delta S-0 = -115 (+/- 10) J mol(-1)K(-1) was obtained. The obtained Delta H-0 value is compared with those reported in the literature for the adsorption of CO2 on other zeolites, and discussed in the context of carbon dioxide capture and sequestration." . . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . "RIV/00216275:25310/14:39898158!RIV15-GA0-25310___" . "The thermodynamics of carbon dioxide adsorption in the protonic zeolite H-MCM-22 (Si:Al = 16:1) was investigated by means of adsorption calorimetry and variable-temperature IR spectroscopy, a technique that affords determination of standard adsorption enthalpy (Delta H-0) and entropy (Delta S-0) from analysis of a series of IR spectra recorded over a temperature range while simultaneously measuring equilibrium pressure inside a closed IR cell. Delta H-0 resulted to be -24.5 (+/- 2) kJ mol(-1), while for the entropy change the value of Delta S-0 = -115 (+/- 10) J mol(-1)K(-1) was obtained. The obtained Delta H-0 value is compared with those reported in the literature for the adsorption of CO2 on other zeolites, and discussed in the context of carbon dioxide capture and sequestration."@en . "316" . "Combined microcalorimetric and IR spectroscopic study on carbon dioxide adsorption in H-MCM-22" . . . . "Zeolites; Thermodynamics; IR spectroscopy; CCS; Carbon dioxide adsorption; Adsorption calorimetry"@en . "Combined microcalorimetric and IR spectroscopic study on carbon dioxide adsorption in H-MCM-22"@en . "2"^^ . . "Combined microcalorimetric and IR spectroscopic study on carbon dioxide adsorption in H-MCM-22" . "[8303D9A22969]" . . . "Applied Surface Science" . . "25310" . . "Frolich, Karel" . "4"^^ . . "10.1016/j.apsusc.2014.08.036" . . . . . "0169-4332" . "October" . "5"^^ . . . .