"RIV/00216275:25310/14:39898096!RIV15-MSM-25310___" . "0022-328X" . . "RIV/00216275:25310/14:39898096" . . "Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands"@en . . . . "Vinkl\u00E1rek, Jarom\u00EDr" . "CO-releasing molecule; Infrared spectroscopy; Pincer ligands; Indenyl effect; Molybdenum compounds"@en . "Honz\u00ED\u010Dkov\u00E1, Iva" . . "Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands" . "Journal of Organometallic Chemistry" . . "Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands" . . "December" . . . "The reactivity of cyclopentadienyl and indenyl molybdenum(II) complexes [(h5-Cp')Mo(CO)2(NCMe)2] [BF4] (Cp' = Cp, Ind, 1,3-Ph2C9H5) with a series of planar N,N,N-chelating ligands was scrutinized. In particular cases a spontaneous release of carbon monoxide to give [(h5-Cp')Mo(CO)(k3-N,N,NL)][BF4] depending on several factors including the basicity of the tridentate ligand as well as the nature of the starting molybdenum(II) compound. This behaviour strongly contrasts with tripodal ligands those do not affect cis-Mo(CO)2 moiety even upon tridentate coordination. All structure types, discussed in this work, were elucidated by the spectroscopic measurements as well as by the X-ray crystallography."@en . "Honz\u00ED\u010Dek, Jan" . "25310" . "[8AFDCEB2A408]" . "Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands"@en . "CH - \u0160v\u00FDcarsk\u00E1 konfederace" . . "10.1016/j.jorganchem.2014.09.028" . "I" . . . "R\u016F\u017Ei\u010Dkov\u00E1, Zde\u0148ka" . "8"^^ . . "000344470100040" . . . "4"^^ . "9516" . "772-773" . . "4"^^ . . "The reactivity of cyclopentadienyl and indenyl molybdenum(II) complexes [(h5-Cp')Mo(CO)2(NCMe)2] [BF4] (Cp' = Cp, Ind, 1,3-Ph2C9H5) with a series of planar N,N,N-chelating ligands was scrutinized. In particular cases a spontaneous release of carbon monoxide to give [(h5-Cp')Mo(CO)(k3-N,N,NL)][BF4] depending on several factors including the basicity of the tridentate ligand as well as the nature of the starting molybdenum(II) compound. This behaviour strongly contrasts with tripodal ligands those do not affect cis-Mo(CO)2 moiety even upon tridentate coordination. All structure types, discussed in this work, were elucidated by the spectroscopic measurements as well as by the X-ray crystallography." . .