. "The reaction of N,C-intramolecularly coordinated organoantimony(III) and organobismuth(III) compounds LMCl2 (M = Sb (1) or Bi (2) and L = [o-(CH=N-2,6-iPr(2)C(6)H(3))C6H4]) with phenyllithium in a 1 : 1 or 1 : 2 molar ratio gave compounds LM(Ph)Cl (M = Sb (3) or Bi (4)) and LMPh2 (M = Sb (5) or Bi (6)) in moderate to good yields. Compound 3 could also be prepared by the treatment of the lithium compound LLi with in situ prepared PhSbCl2. Oxidation of the antimony(III) compounds 1, 3 and 5 with one equivalent of SO2Cl2 proceeded smoothly with formation of organoantimony(V) compounds LSbCl4 (7), LSb(Ph)Cl-3 (8) and LSbPh2Cl2 (9) in nearly quantitative yields. Compounds 7-9 are yellowish solids that are stable for a long time even in the presence of air. In contrast, only organobismuth(III) compounds 4 and 6 could be successfully oxidized using SO2Cl2 to give compounds LBi(Ph)Cl-3 (10) and LBiPh2Cl2 (11). Compound 11 is stable, but compound 10 readily decomposed in solution and could not be isolated and stored for a longer period. All attempts to prepare compound LBiCl4 by the oxidation of 2 with SO2Cl2 failed and resulted only in a mixture of products. All studied compounds were characterized by electrospray ionization (ESI) mass spectrometry, and H-1 and C-13 NMR spectroscopy. The molecular structures of 3-7, 9 and 11 were unambiguously established using single-crystal X-ray diffraction analysis." . "Dost\u00E1l, Libor" . "Jambor, Roman" . . . . . "efficient; derivatives; r=2-(me2nch2)c6h4; complexes; coordination; ligands; carbon-dioxide; dynamic-behavior; chelated organoantimony(iii); bond covalent radii"@en . "1477-9226" . . "5"^^ . . "RIV/00216275:25310/14:39896785!RIV15-MSM-25310___" . . "43" . "The reaction of N,C-intramolecularly coordinated organoantimony(III) and organobismuth(III) compounds LMCl2 (M = Sb (1) or Bi (2) and L = [o-(CH=N-2,6-iPr(2)C(6)H(3))C6H4]) with phenyllithium in a 1 : 1 or 1 : 2 molar ratio gave compounds LM(Ph)Cl (M = Sb (3) or Bi (4)) and LMPh2 (M = Sb (5) or Bi (6)) in moderate to good yields. Compound 3 could also be prepared by the treatment of the lithium compound LLi with in situ prepared PhSbCl2. Oxidation of the antimony(III) compounds 1, 3 and 5 with one equivalent of SO2Cl2 proceeded smoothly with formation of organoantimony(V) compounds LSbCl4 (7), LSb(Ph)Cl-3 (8) and LSbPh2Cl2 (9) in nearly quantitative yields. Compounds 7-9 are yellowish solids that are stable for a long time even in the presence of air. In contrast, only organobismuth(III) compounds 4 and 6 could be successfully oxidized using SO2Cl2 to give compounds LBi(Ph)Cl-3 (10) and LBiPh2Cl2 (11). Compound 11 is stable, but compound 10 readily decomposed in solution and could not be isolated and stored for a longer period. All attempts to prepare compound LBiCl4 by the oxidation of 2 with SO2Cl2 failed and resulted only in a mixture of products. All studied compounds were characterized by electrospray ionization (ESI) mass spectrometry, and H-1 and C-13 NMR spectroscopy. The molecular structures of 3-7, 9 and 11 were unambiguously established using single-crystal X-ray diffraction analysis."@en . . . "R\u016F\u017Ei\u010Dka, Ale\u0161" . "5"^^ . . . "Synthesis and structure of N,C-chelated organoantimony(V) and organobismuth(V) compounds"@en . . . "000327894400017" . . "2" . . "I, P(GA13-00289S)" . "25310" . . "[56DF3CDEC245]" . "GB - Spojen\u00E9 kr\u00E1lovstv\u00ED Velk\u00E9 Brit\u00E1nie a Severn\u00EDho Irska" . "Jir\u00E1sko, Robert" . "Dalton Transactions" . "RIV/00216275:25310/14:39896785" . . "10.1039/c3dt51733k" . "Vr\u00E1nov\u00E1, Iva" . . . "Synthesis and structure of N,C-chelated organoantimony(V) and organobismuth(V) compounds" . "Synthesis and structure of N,C-chelated organoantimony(V) and organobismuth(V) compounds" . . "48990" . . . . . . "8"^^ . "Synthesis and structure of N,C-chelated organoantimony(V) and organobismuth(V) compounds"@en . .