"US - Spojen\u00E9 st\u00E1ty americk\u00E9" . "0276-7333" . . . "http://pubs.acs.org/doi/abs/10.1021/om400082t" . "Stabilization of Three-Coordinated Germanium(II) and Tin(II) Cations by a Neutral Chelating Ligand"@en . "RIV/00216275:25310/13:39896296" . "Bou\u0161ka, Marek" . . . "[25442B1E420F]" . . "Treatment of the neutral 2-[C(CH3)=N(C6H3-2,6-Pr-i(2))]-6-(CH3O)C6H3N ligand (hereafter assigned as L) with SnCl2 and GeCl2 provided the ionic germanium(II) and tin(II) complexes [(LGeCl)-Cl-II](+)[(GeCl3)-Cl-II](-) (1) and [(LSnCl)-Cl-II](+)[(SnCl3)-Cl-II](-) (2), respectively, as the result of spontaneous dissociation of ECl2 (E = Ge, Sn). The cationic parts [(LECl)-Cl-II](+) of 1 and 2 contain three-coordinated germanium(II) and tin(II) atoms. In comparison, treatment of the ligand L with GeCl4, and SnBr4 yielded the germanium(IV) and tin(IV) complexes LGeCl4 (3) and LSnBr4 (4), respectively, and no dissociation process was observed. Compounds 1-4 were characterized by means of elemental analyses, H-1, C-13, and Sn-119 NMR spectroscopies, and single-crystal X-ray diffraction analysis in (compounds 1 and 4)."@en . "Stabilization of Three-Coordinated Germanium(II) and Tin(II) Cations by a Neutral Chelating Ligand" . "activation; coordination; complexes; tin cations"@en . . "Jambor, Roman" . "Stabilization of Three-Coordinated Germanium(II) and Tin(II) Cations by a Neutral Chelating Ligand"@en . . "R\u016F\u017Ei\u010Dka, Ale\u0161" . "25310" . "Stabilization of Three-Coordinated Germanium(II) and Tin(II) Cations by a Neutral Chelating Ligand" . . "I, S" . . "10.1021/om400082t" . "Treatment of the neutral 2-[C(CH3)=N(C6H3-2,6-Pr-i(2))]-6-(CH3O)C6H3N ligand (hereafter assigned as L) with SnCl2 and GeCl2 provided the ionic germanium(II) and tin(II) complexes [(LGeCl)-Cl-II](+)[(GeCl3)-Cl-II](-) (1) and [(LSnCl)-Cl-II](+)[(SnCl3)-Cl-II](-) (2), respectively, as the result of spontaneous dissociation of ECl2 (E = Ge, Sn). The cationic parts [(LECl)-Cl-II](+) of 1 and 2 contain three-coordinated germanium(II) and tin(II) atoms. In comparison, treatment of the ligand L with GeCl4, and SnBr4 yielded the germanium(IV) and tin(IV) complexes LGeCl4 (3) and LSnBr4 (4), respectively, and no dissociation process was observed. Compounds 1-4 were characterized by means of elemental analyses, H-1, C-13, and Sn-119 NMR spectroscopies, and single-crystal X-ray diffraction analysis in (compounds 1 and 4)." . . . "4"^^ . . "000316773800054" . . "6" . "107409" . "4"^^ . "RIV/00216275:25310/13:39896296!RIV14-MSM-25310___" . "5"^^ . "32" . . . "Organometallics" . . . . . . "Dost\u00E1l, Libor" .