. "Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic" . . "10.1021/om201025d" . "Dost\u00E1l, Libor" . . "R\u016F\u017Ei\u010Dka, Ale\u0161" . . "Jir\u00E1sko, Robert" . . "Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic"@en . "5" . "5"^^ . . "6"^^ . . . "Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic" . "De Proft, Frank" . . . "US - Spojen\u00E9 st\u00E1ty americk\u00E9" . "[CE1C53A293EC]" . "7"^^ . . "Ly\u010Dka, Anton\u00EDn" . . "25310" . . "Svoboda, Tom\u00E1\u0161" . "PH; ORGANOANTIMONY(III); ELEMENTS; CRYSTAL-STRUCTURES; GAUSSIAN-BASIS SETS; CORRELATED MOLECULAR CALCULATIONS; BOND COVALENT RADII"@en . "Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic"@en . . "0276-7333" . . . "Jambor, Roman" . . . . "31" . . . "Organoantimony(III) and organobismuth(III) oxides (LMO)(2) (where L is the NCN-chelating ligand C6H3-2,6-(CH2NMe2)(2) and M = Sb (1), Bi (2)) reacted smoothly with arsenic oxides As2O5 and As2O3 to form the molecular oxides [(LM)(3)(AsO4)(2)] and [(LM)(2)(As2O5)] (where M = Sb (3, 5), Bi (4, 6)). All compounds were characterized by electrospray ionization (ESI) mass spectrometry, nuclear magnetic resonance (NMR) spectroscopy, and, in the case of and 6, single-crystal X-ray diffraction (XRD) analyses. Compound 3 formed two conformational isomers in a benzene or chloroform solution, as confirmed by H-1 and C-13 NMR spectroscopy. As in the case of 3, 5 also formed conformational isomers in a benzene solution, whereas the bismuth analogue 6 was unstable in solution. The stabilities of the three possible conformers of 5 were studied by density functional theory (DFT) calculations." . . . . "000301331200019" . "Organometallics" . . "RIV/00216275:25310/12:39895564!RIV13-GA0-25310___" . "RIV/00216275:25310/12:39895564" . "I, P(GAP106/10/0443), S" . . "Organoantimony(III) and organobismuth(III) oxides (LMO)(2) (where L is the NCN-chelating ligand C6H3-2,6-(CH2NMe2)(2) and M = Sb (1), Bi (2)) reacted smoothly with arsenic oxides As2O5 and As2O3 to form the molecular oxides [(LM)(3)(AsO4)(2)] and [(LM)(2)(As2O5)] (where M = Sb (3, 5), Bi (4, 6)). All compounds were characterized by electrospray ionization (ESI) mass spectrometry, nuclear magnetic resonance (NMR) spectroscopy, and, in the case of and 6, single-crystal X-ray diffraction (XRD) analyses. Compound 3 formed two conformational isomers in a benzene or chloroform solution, as confirmed by H-1 and C-13 NMR spectroscopy. As in the case of 3, 5 also formed conformational isomers in a benzene solution, whereas the bismuth analogue 6 was unstable in solution. The stabilities of the three possible conformers of 5 were studied by density functional theory (DFT) calculations."@en . . "164202" .