"2012" . "Diphosphastannylenes: Precursors for Phosphorus-Phosphorus Coupling?"@en . "DE - Spolkov\u00E1 republika N\u011Bmecko" . "The preparation of the secondary phosphane (Ph){C6H3-2,6-(CH2NMe2)2}PH (1), a potentially base-stabilized ligand, and the sterically protected carbaborane-based phosphane (o-CH3C2B10H10)2PH (2) is reported. Reaction of Sn{N(SiMe3)}2 with 1 gives the diphosphastannylene [(Ph){(C6H3-2,6-CH2NMe2)2}P]2Sn (3) in high yield. In contrast, the room-temperature reaction of 2 with Sn{N(SiMe2)}2 does not proceed. By applying elevated temperatures, the heteroleptic amidophosphastannylene {(o-CH3C2B10H10)2P}{(SiMe3)2N}Sn (4) was formed, instead of the expected diphosphastannylene {(o-CH3C2B10H10)2P}2Sn. The thermal decomposition of compounds 3 and 4 was also studied. The thermal decomposition of 3 produced the new phosphorusphosphorus-bonded compound 5, an unprecedented 1,2-diphosphol-type molecule." . "Dost\u00E1l, Libor" . . "R\u016F\u017Ei\u010Dka, Ale\u0161" . "1434-1948" . . . "Jambor, Roman" . "131400" . "10.1002/ejic.201200375" . "I, P(GAP207/10/0215), S" . "The preparation of the secondary phosphane (Ph){C6H3-2,6-(CH2NMe2)2}PH (1), a potentially base-stabilized ligand, and the sterically protected carbaborane-based phosphane (o-CH3C2B10H10)2PH (2) is reported. Reaction of Sn{N(SiMe3)}2 with 1 gives the diphosphastannylene [(Ph){(C6H3-2,6-CH2NMe2)2}P]2Sn (3) in high yield. In contrast, the room-temperature reaction of 2 with Sn{N(SiMe2)}2 does not proceed. By applying elevated temperatures, the heteroleptic amidophosphastannylene {(o-CH3C2B10H10)2P}{(SiMe3)2N}Sn (4) was formed, instead of the expected diphosphastannylene {(o-CH3C2B10H10)2P}2Sn. The thermal decomposition of compounds 3 and 4 was also studied. The thermal decomposition of 3 produced the new phosphorusphosphorus-bonded compound 5, an unprecedented 1,2-diphosphol-type molecule."@en . . . "Diphosphastannylenes: Precursors for Phosphorus-Phosphorus Coupling?" . . . . "RIV/00216275:25310/12:39894829" . . "4"^^ . . "25310" . . "5"^^ . "Diphosphastannylenes: Precursors for Phosphorus-Phosphorus Coupling?"@en . . . . . "Diphosphastannylenes: Precursors for Phosphorus-Phosphorus Coupling?" . . "\u0158ezn\u00ED\u010Dek, Tom\u00E1\u0161" . . "X ray diffraction; NMR spectroscopy; P-P coupling; P ligands; Tin"@en . "000305122000003" . "4"^^ . "European Journal of Inorganic Chemistry" . . . "RIV/00216275:25310/12:39894829!RIV13-GA0-25310___" . . "18" . . "[7229D13DFB59]" . . .