"[412BE8E4D29D]" . "R\u00F6sslerov\u00E1, Ivana" . "Lead borophosphate glasses doped with MoO3 with different ratio of B2O3/P2O5 were prepared. Glasses were studied in the dependence on the MoO3 content in compositional series (1-x)[50PbO-10B2O3-40P2O5]-xMoO3 in the range of 0-70 mol% MoO3 and in the compositional series (1-x)[50PbO-yB2O3-(50-y)P2O5]-xMoO3 with the B2O3/P2O5 ratio equal to 5/45, 10/40 and 15/35 at the MoO3 content 0, 20, 40 and 60 mol%. 31P MAS NMR spectra showed on the depolymerization of phosphate network by the incorporation of molybdate structural units. 11B MAS NMR spectra revealed the formation of mixed structural units with B-O-Mo bonds - B(OP)3(OMo) and B(OP)2(OMo)2, the content of which increases with increasing MoO3 content as well as the number of trigonal BO3 units. Raman spectra revealed formation of molybdate clusters formed by MoO6 octahedra interconnected by Mo-O-Mo bonds."@en . "2011-11-30+01:00"^^ . . . "\u010Cesk\u00E1 skl\u00E1\u0159sk\u00E1 spole\u010Dnost" . "STRUKTURA A VLASTNOSTI BOROFOSF\u00C1TOV\u00DDCH SKEL OLOVNAT\u00DDCH DOTOVAN\u00DDCH OXIDEM MOLYBDENOV\u00DDM" . "Borofosf\u00E1tov\u00E1 skla olovnat\u00E1 modifikovan\u00E1 oxidem molybdenov\u00FDm s r\u016Fzn\u00FDm po\u00E9m\u011Brem B2O3/P2O5 byla p\u0159ipravena a studov\u00E1na v kompozi\u010Dn\u00EDch \u0159ad\u00E1ch 1-x)[50PbO-10B2O3-40P2O5]-xMoO3 s obsahem 0-70 mol% MoO3 and v \u0159ad\u00E1ch 1-x)[50PbO-yB2O3-(50-y)P2O5]-xMoO3 s pom\u011Brem B2O3/P2O5 5/45, 10/40 a 15/35 a obsahem MoO3 rov\u00FDm 0, 20, 40 and 60 mol%. 31P MAS NMR spektra uk\u00E1zala na depolymerizaci fosf\u00E1tov\u00FDch \u0159et\u011Bzc\u016F vestavov\u00E1n\u00EDm molybd\u00E1tov\u00FDch celk\u016F. 11B MAS NMR spectra uk\u00E1zala na tvorbu sm\u011Bsn\u00FDch strukturn\u00EDch celk\u016F s vazbami B-O-Mo - B(OP)3(OMo) a B(OP)2(OMo)2, jejich\u017E po\u010Det roste s r\u016Fstem obsahu MoO3, stejn\u011B tak jako po\u010Det trigon\u00E1ln\u00EDch strkturn\u00EDch celk\u016F BO3. Ramanova spektra uk\u00E1zala na tvorbu molybd\u00E1tov\u00FDch klastr\u016F z oktaedrick\u00FDch celk\u016F MoO6 propojen\u00FDch vazbami Mo-O-Mo." . "S, Z(MSM0021627501)" . . . . "25310" . . . . . "STRUKTURA A VLASTNOSTI BOROFOSF\u00C1TOV\u00DDCH SKEL OLOVNAT\u00DDCH DOTOVAN\u00DDCH OXIDEM MOLYBDENOV\u00DDM"@cs . . "Zborn\u00EDk pr\u00EDspevkov, zvl\u00E1\u0161tn\u00ED \u010D\u00EDslo \u010Dasopisu Skl\u00E1\u0159 a keramik, ro\u010Dn\u00EDk 61 (2011)" . "Tren\u010Dianske Teplice" . "3"^^ . . . . . . "properties; structure; Raman; NMR; glasses"@en . "3"^^ . "STRUKTURA A VLASTNOSTI BOROFOSF\u00C1TOV\u00DDCH SKEL OLOVNAT\u00DDCH DOTOVAN\u00DDCH OXIDEM MOLYBDENOV\u00DDM" . "Borofosf\u00E1tov\u00E1 skla olovnat\u00E1 modifikovan\u00E1 oxidem molybdenov\u00FDm s r\u016Fzn\u00FDm po\u00E9m\u011Brem B2O3/P2O5 byla p\u0159ipravena a studov\u00E1na v kompozi\u010Dn\u00EDch \u0159ad\u00E1ch 1-x)[50PbO-10B2O3-40P2O5]-xMoO3 s obsahem 0-70 mol% MoO3 and v \u0159ad\u00E1ch 1-x)[50PbO-yB2O3-(50-y)P2O5]-xMoO3 s pom\u011Brem B2O3/P2O5 5/45, 10/40 a 15/35 a obsahem MoO3 rov\u00FDm 0, 20, 40 and 60 mol%. 31P MAS NMR spektra uk\u00E1zala na depolymerizaci fosf\u00E1tov\u00FDch \u0159et\u011Bzc\u016F vestavov\u00E1n\u00EDm molybd\u00E1tov\u00FDch celk\u016F. 11B MAS NMR spectra uk\u00E1zala na tvorbu sm\u011Bsn\u00FDch strukturn\u00EDch celk\u016F s vazbami B-O-Mo - B(OP)3(OMo) a B(OP)2(OMo)2, jejich\u017E po\u010Det roste s r\u016Fstem obsahu MoO3, stejn\u011B tak jako po\u010Det trigon\u00E1ln\u00EDch strkturn\u00EDch celk\u016F BO3. Ramanova spektra uk\u00E1zala na tvorbu molybd\u00E1tov\u00FDch klastr\u016F z oktaedrick\u00FDch celk\u016F MoO6 propojen\u00FDch vazbami Mo-O-Mo."@cs . "Vl\u010Dek, Miroslav" . "Structure and properties of lead borophosphate glasses modified by molybdenum oxide"@en . "232837" . "978-80-260-1068-5" . . . . "STRUKTURA A VLASTNOSTI BOROFOSF\u00C1TOV\u00DDCH SKEL OLOVNAT\u00DDCH DOTOVAN\u00DDCH OXIDEM MOLYBDENOV\u00DDM"@cs . "RIV/00216275:25310/11:39892398!RIV12-MSM-25310___" . . . . "RIV/00216275:25310/11:39892398" . "Structure and properties of lead borophosphate glasses modified by molybdenum oxide"@en . . "Teplice" . "5"^^ . "Koudelka, Ladislav" .