"Electroanalytical Investigation of Homocysteine and the Respective Thiolactone Using Cathodic Stripping Voltammetry with a Mercury Electrode" . . . "Ljubljana, Slovenia" . . "In the regime of anodic polarization at a mercury electrode, homocysteine forms a sparingly soluble mercury thiolate and the reduction of mercury ion in this compound gives rise to a characteristic cathodic stripping peak A. If the nickel ion is present, homocysteine released by this reaction does catalyze nickel ion reduction and yields a second cathodic signal (peak B) with no influence on peak A. Homocysteine thiolactone is electrochemically inactive under such conditions, so the homocysteine inpurity in thiolactone can be easily assayed." . . . . "RIV/00216275:25310/08:00007985!RIV09-MSM-25310___" . "Electroanalytical Investigation of Homocysteine and the Respective Thiolactone Using Cathodic Stripping Voltammetry with a Mercury Electrode"@en . "365760" . "978-961-6286-96-1" . "2008-07-05+02:00"^^ . . . "University of Ljublana" . . "Vyt\u0159as, Karel" . . . "7"^^ . . "Banica, F. G." . . "Electroanalytical Investigation of Homocysteine and the Respective Thiolactone Using Cathodic Stripping Voltammetry with a Mercury Electrode"@en . "3"^^ . "Fischer, Jan" . "P(LC06035), Z(MSM0021627502)" . . "Banica, Ana" . "In the regime of anodic polarization at a mercury electrode, homocysteine forms a sparingly soluble mercury thiolate and the reduction of mercury ion in this compound gives rise to a characteristic cathodic stripping peak A. If the nickel ion is present, homocysteine released by this reaction does catalyze nickel ion reduction and yields a second cathodic signal (peak B) with no influence on peak A. Homocysteine thiolactone is electrochemically inactive under such conditions, so the homocysteine inpurity in thiolactone can be easily assayed."@en . "RIV/00216275:25310/08:00007985" . "Gal\u00EDk, Michal" . "25310" . "4"^^ . "[0C9E680BA5F5]" . "\u0160vancara, Ivan" . "Studium elektroanalytick\u00FDch vlastnost\u00ED homocysteinu a jeho thiolaktonu na rtu\u0165ov\u00E9 elektrod\u011B s vyu\u017Eit\u00EDm katodick\u00E9 rozpou\u0161t\u011Bc\u00ED voltametrie"@cs . . "P\u0159i anodick\u00E9 polarizaci na rtu\u0165ov\u00E9 elektrod\u011B vytv\u00E1\u0159\u00ED homocystein m\u00E1lo rozpustn\u00FD thiol\u00E1t rtu\u0165nat\u00FD a redukce iontu rtuti v t\u00E9to slou\u010Denin\u011B poskytuje charakteristick\u00FD katodick\u00FD rozpou\u0161t\u011Bc\u00ED p\u00EDk A. V p\u0159\u00EDtomnosti nikelnat\u00FDch iont\u016F katalyzuje uvoln\u011Bn\u00FD homocystein jejich redukci a registruje se druh\u00FD katodick\u00FD sign\u00E1l (peak B). Tento proces neovliv\u0148uje p\u00EDk A. Thiolakton homocysteinu nen\u00ED za uveden\u00FDch podm\u00EDnek elektrochemicky aktivn\u00ED a lze tak v n\u011Bm sledovat p\u0159\u00EDtomnost homocysteinu jako ne\u010Distoty."@cs . "Studium elektroanalytick\u00FDch vlastnost\u00ED homocysteinu a jeho thiolaktonu na rtu\u0165ov\u00E9 elektrod\u011B s vyu\u017Eit\u00EDm katodick\u00E9 rozpou\u0161t\u011Bc\u00ED voltametrie"@cs . . "\u010Cesla, Petr" . . . . "homocysteine; homocysteine thiolaktone; mercury electrode; cathodic stripping voltammetry"@en . "Ljublana" . . "Electroanalytical Investigation of Homocysteine and the Respective Thiolactone Using Cathodic Stripping Voltammetry with a Mercury Electrode" . . "YISAC 2008: 15th Young Investigators' Seminar on Analytical Chemistry" . .