"2005-07-04+02:00"^^ . "25310" . . . . . "1"^^ . "\u0160im\u016Fnek, Petr" . "952-10-2553-0" . "5"^^ . "3-Amino-1-phenyl-2-(4-dimethylaminophenyldiazenyl)but-2-en-1-on jako hostitelsk\u00E1 molekula pro n\u011Bkter\u00E9 aromatick\u00E9 slou\u010Deniny"@cs . "Enaminony (beta-enaminoketony) jsou slou\u010Deniny \u0161iroce vyu\u017E\u00EDvan\u00E9 v organick\u00E9 chemii, p\u0159edev\u0161\u00EDm pro synt\u00E9zy heterocyklick\u00FDch l\u00E1tek. Jejich reakce s r\u016Fzn\u00FDmi benzendiazoniov\u00FDmi solemi vede k azokopulovan\u00FDm slou\u010Denin\u00E1m nap\u0159. (3), kter\u00E9 vykazuj\u00ED zaj\u00EDmav\u00E9 vlastnosti z hlediska struktur\u00E1ln\u00ED organick\u00E9 chemie. Slou\u010Denina (3) p\u0159ipraven\u00E1 azokopula\u010Dn\u00ED reakc\u00ED beta-enaminonu, jen\u017E vznikl kondenza\u010Dn\u00ED reakc\u00ED p\u0159\u00EDslu\u0161n\u00E9ho diketonu a amoniaku (Sch\u00E9ma 1), se zd\u00E1 b\u00FDt vhodnou hostitelskou molekulou, kter\u00E1 v\u00E1\u017Ee ve sv\u00E9 krystalov\u00E9 m\u0159\u00ED\u017Ece n\u011Bkter\u00E9 aromatick\u00E9 slou\u010Deniny, nap\u0159. benzen, toluen, p-xylen a chlorbenzen. V pevn\u00E9m stavu jsou jednotliv\u00E9 molekuly (3) spojeny intermolekul\u00E1rn\u00EDmi vod\u00EDkov\u00FDmi vazbami1 a tvo\u0159\u00ED tunely, v nich\u017E jsou uzav\u0159eny aromatick\u00E9 slou\u010Deniny (nap\u0159. molekula toluenu Obr. 2)."@cs . . "University of Helsinki" . "Helsinki (Finland)" . "3-Amino-2-(4-dimethylaminophenyldiazenyl)-1-phenylbut-2-en-1-one as a host molecule for some aromatic compounds"@en . "Helsinki (Finland)" . . "Ly\u010Dka, Anton\u00EDn" . "RIV/00216275:25310/05:00003065!RIV08-MSM-25310___" . . "3-Amino-2-(4-dimethylaminophenyldiazenyl)-1-phenylbut-2-en-1-one as a host molecule for some aromatic compounds" . "Bertolasi, Valerio" . . . "3-Amino-2-(4-dimethylaminophenyldiazenyl)-1-phenylbut-2-en-1-one as a host molecule for some aromatic compounds"@en . . . . . . "14th European Symposium on Organic Chemistry" . "3-Amino-1-phenyl-2-(4-dimethylaminophenyldiazenyl)but-2-en-1-on jako hostitelsk\u00E1 molekula pro n\u011Bkter\u00E9 aromatick\u00E9 slou\u010Deniny"@cs . "Pe\u0161kov\u00E1, Mark\u00E9ta" . "552717" . "P(GA203/03/0356), Z(MSM0021627501)" . "Enaminones; diazonium salts; azo coupling; X-ray."@en . "[376F655427FC]" . "Enaminones (beta-enaminoketones) are compounds widely used in organic chemistry, namely for heterocyclic syntheses. Their reaction with various benzenediazonium salts leads to azo coupled compounds e.g. (3) having interesting properties from structural organic chemistry?s view. The title compound (3), prepared by condensation of appropriate beta-diketone and ammonia and by subsequent azo coupling (Scheme 1), appeared to be a host molecule forming inclusion compounds with some aromatic such as benzene, toluene, p-xylene, chlorobenzene. In crystalline state molecules (3) are linked together by intermolecular hydrogen bonds1 forming channels where the molecules of the aromatic compounds are included (for the case of toluene see Fig. 2)."@en . . "Mach\u00E1\u010Dek, Vladim\u00EDr" . . "3"^^ . "Enaminones (beta-enaminoketones) are compounds widely used in organic chemistry, namely for heterocyclic syntheses. Their reaction with various benzenediazonium salts leads to azo coupled compounds e.g. (3) having interesting properties from structural organic chemistry?s view. The title compound (3), prepared by condensation of appropriate beta-diketone and ammonia and by subsequent azo coupling (Scheme 1), appeared to be a host molecule forming inclusion compounds with some aromatic such as benzene, toluene, p-xylene, chlorobenzene. In crystalline state molecules (3) are linked together by intermolecular hydrogen bonds1 forming channels where the molecules of the aromatic compounds are included (for the case of toluene see Fig. 2)." . . "206" . . "RIV/00216275:25310/05:00003065" . . . . "3-Amino-2-(4-dimethylaminophenyldiazenyl)-1-phenylbut-2-en-1-one as a host molecule for some aromatic compounds" .